N-METHYLDIHEXYLAMINE

Base Information

• Chemical Name: N-METHYLDIHEXYLAMINE
• CAS No.: 37615-53-5
• Molecular Formula: C13H29 N
• Molecular Weight: 199.38
• Hs Code.: 2921199090
• Mol file: 37615-53-5.mol

Synonyms:Dihexylamine,N-methyl- (6CI); Dihexylmethylamine; Methyldihexylamine;N,N-Dihexyl-N-methylamine; N-Methyldihexylamine

Chemical Property of N-METHYLDIHEXYLAMINE

Chemical Property:

• Vapor Pressure: 0.0356mmHg at 25°C
• Melting Point: 26°C (estimate)
• Refractive Index: n20/D 1.433(lit.)
• Boiling Point: 241.6°Cat760mmHg
• PKA: 10.23±0.50(Predicted)
• Flash Point: 89.9°C
• PSA: 3.24000
• Density: 0.796g/cm³
• LogP: 4.07880

Purity/Quality:

98%Min ^*data from raw suppliers

N-Methyldihexylamine ≥97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: N-Methyldihexylamine may be used to synthesize comb-shaped cationic poly(2,6-dimethylphenylenoxide) (PPO) polymer anion-exchange membrane (AEM) containing two hexyl side chains.

Technology Process of N-METHYLDIHEXYLAMINE

There total 7 articles about N-METHYLDIHEXYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-methylhexanamine (35161-70-7) → N,N-dimethylhexylamine (4385-04-0) + N,N-dihexyl-N-methylamine (37615-53-5)

Guidance literature:

With tris(triphenylphosphine)ruthenium(II) chloride; In tetrahydrofuran; at 180 ℃; for 7h;

DOI:10.1016/S0022-328X(00)81961-0

Reference yield:

methanol (67-56-1) + hexan-1-amine (111-26-2) → N,N-dimethylhexylamine (4385-04-0) + dihexylamine (143-16-8) + N,N-dihexyl-N-methylamine (37615-53-5) + tri-n-hexylamine (102-86-3)

Guidance literature:

With tris(triphenylphosphine)ruthenium(II) chloride; at 180 ℃; for 7h;

DOI:10.1016/S0022-328X(00)85724-1

Reference yield:

1-bromo-hexane (111-25-1) + methylamine (74-89-5) → N-methylhexanamine (35161-70-7) + N,N-dihexyl-N-methylamine (37615-53-5)

Guidance literature:

With ethanol;

DOI:10.1021/ja01873a004

upstream raw materials:

1-Chlorohexane

methylamine

1-bromo-hexane

methanol

Downstream raw materials:

(cyanomethyl)dihexylmethylammonium tosylate

Refernces

• 1、 Arcelli, Antonio,Khai, Bui-The,Porzi, Gianni. "SELECTIVE CONVERSION OF PRIMARY AMINES INRO N,N-DIMETHYLALKYL- OR N,N-DIALKYLMETHYL-AMINES WITH METHANOL AND RuCl2(Ph3P)3". . p. 93 - 96. Retrieved 2007/10/02.