5,10,15,20-TETRAKIS(2,6-DICHLOROPHENYL)PORPHINE

Base Information

• Chemical Name: 5,10,15,20-TETRAKIS(2,6-DICHLOROPHENYL)PORPHINE
• CAS No.: 37083-37-7
• Molecular Formula: C44H22 Cl8 N4
• Molecular Weight: 890.309
• Hs Code.: 2933998090
• Mol file: 37083-37-7.mol

Synonyms:5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin;5,10,15,20-tetrakis(2,6-dichlorophenyl)-21H,23H-porphine;meso-Tetrakis(2,6-dichlorophenyl)porphine;meso-Tetrakis(2,6-dichlorophenyl)porphyrin

Chemical Property of 5,10,15,20-TETRAKIS(2,6-DICHLOROPHENYL)PORPHINE

Chemical Property:

• Refractive Index: 1.706
• PSA: 56.30000
• Density: 1.519g/cm³
• LogP: 12.09340
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

meso-Tetrakis(2,6-dichlorophenyl)porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: meso-Tetrakis(2,6-dichlorophenyl)porphine is a photosensitizer that is often used to create coordination complexes with metals such as ruthenium and palladium. meso-Tetrakis(2,6-dichlorophenyl)porphine is also being used as an environmentally friendly photocatalyst to degrade pesticides in soils.

Technology Process of 5,10,15,20-TETRAKIS(2,6-DICHLOROPHENYL)PORPHINE

There total 27 articles about 5,10,15,20-TETRAKIS(2,6-DICHLOROPHENYL)PORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

pyrrole (109-97-7,30604-81-0) + 2,6-dichlorobenzaldehyde (83-38-5) → 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (37083-37-7)

Guidance literature:

pyrrole; 2,6-dichlorobenzaldehyde; With Tulsion-63 resin; Triethyl orthoacetate; In dichloromethane; at 20 ℃; for 17h;

With chloranil; In dichloromethane; for 2h; Heating;

DOI:10.1016/S0040-4020(03)00245-X

Reference yield: 22.0%

2,6-dichlorobenzaldehyde (83-38-5) + 5,10-bis(2,6-dichlorophenyl)tripyrromethane → 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (37083-37-7) + hexakis(2,6-dichlorophenyl) [26]hexaphyrin (1.1.1.1.1.1) (884530-85-2) + heptakis(2,6-dichlorophenyl) substituted [32]heptaphyrin(1.1.1.1.1.1.1) + C99H51Cl18N9

Guidance literature:

2,6-dichlorobenzaldehyde; 5,10-bis(2,6-dichlorophenyl)tripyrromethane; With methanesulfonic acid; In dichloromethane; at 0 ℃; for 2h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone;

DOI:10.1016/S0040-4039(03)00328-9

Reference yield: 19.0%

2,6-dichlorobenzaldehyde (83-38-5) + (2,6-dichlorophenyl)dipyrrol-2-ylmethane (194796-34-4) → 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (37083-37-7) + hexakis(2,6-dichlorophenyl) [26]hexaphyrin (1.1.1.1.1.1) (884530-85-2)

Guidance literature:

With sulfonated graphene; In 1,2-dichloro-benzene; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1007/s12039-014-0731-8

upstream raw materials:

pyrrole

2-chloro-6-methoxybenzaldehyde

2,6-dichlorobenzaldehyde

2-chloro-6-nitrobenzaldehyde

Downstream raw materials:

5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin

chloro(meso-tetrakis(2,6-dichlorophenyl)porphyrinato)manganese(III)

Refernces

• 1、 Chorghade,Dolphin,Dupre,Hill,Lee,Wijesekera. "Improved protocols for the synthesis and halogenation of sterically hindered metalloporphyrins". . p. 1320 - 1324. Retrieved 1996.
• 2、 Shen, Hai-Min,Qi, Bei,Hu, Meng-Yun,Liu, Lei,Ye, Hong-Liang,She, Yuan-Bin. "Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C–H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N-Hydroxyphthalimide". . p. 3096 - 3111. Retrieved 2020/04/29.
• 3、 Henriques, César A.,Fernandes, Auguste,Rossi, Liane M.,Ribeiro, M. Filipa,Calvete, Mário J. F.,Pereira, Mariette M.. "Biologically Inspired and Magnetically Recoverable Copper Porphyrinic Catalysts: A Greener Approach for Oxidation of Hydrocarbons with Molecular Oxygen". . p. 3359 - 3368. Retrieved 2016/06/06.