C₁₂H₇N₂OS₄

Base Information

• Chemical Name: C₁₂H₇N₂OS₄
• CAS No.: 1306755-09-8
• Molecular Formula: C₁₂H₇N₂OS₄
• Molecular Weight: 323.464
• Mol file: 1306755-09-8.mol

Synonyms:C₁₂H₇N₂OS₄

Chemical Property of C₁₂H₇N₂OS₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₂H₇N₂OS₄

There total 5 articles about C₁₂H₇N₂OS₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

[2a][OTf] → C12H7N2OS4 (1306755-09-8)

Guidance literature:

With octamethylferrocene; In acetonitrile; for 15h;

DOI:10.1039/c1cc10598a

Reference yield:

4-Phenylphenol (92-69-3) → C12H7N2OS4 (1306755-09-8)

Guidance literature:

Multi-step reaction with 5 steps

1: nitric acid; acetic acid / 0.75 h / Cooling with ice

2: hydrogenchloride; tin; tin(II) chloride hydrate / ethanol / 0.5 h / 0 °C

3: disulfur dichloride / acetonitrile / Reflux

4: acetonitrile / 1 h / Heating

5: octamethylferrocene / acetonitrile / 15 h

With hydrogenchloride; disulfur dichloride; tin; tin(II) chloride hydrate; nitric acid; acetic acid; In ethanol; acetonitrile; 3: Herz cyclization;

DOI:10.1039/c1cc10598a

Reference yield:

4-hydroxy-3,5-dinitrobiphenyl (4097-53-4) → C12H7N2OS4 (1306755-09-8)

Guidance literature:

Multi-step reaction with 4 steps

1: hydrogenchloride; tin; tin(II) chloride hydrate / ethanol / 0.5 h / 0 °C

2: disulfur dichloride / acetonitrile / Reflux

3: acetonitrile / 1 h / Heating

4: octamethylferrocene / acetonitrile / 15 h

With hydrogenchloride; disulfur dichloride; tin; tin(II) chloride hydrate; In ethanol; acetonitrile; 2: Herz cyclization;

DOI:10.1039/c1cc10598a

upstream raw materials:

4-Phenylphenol

4-hydroxy-3,5-dinitrobiphenyl

Refernces