[Ru(C(CCPh)=CHPh)(CO)(PPh₃)2(piperazine dithiocarbamate)]Cl

Base Information

• Chemical Name: [Ru(C(CCPh)=CHPh)(CO)(PPh₃)2(piperazine dithiocarbamate)]Cl
• CAS No.: 1092555-74-2
• Molecular Formula: C₅₈H₅₁N₂OP₂RuS₂*Cl
• Molecular Weight: 1054.66
• Mol file: 1092555-74-2.mol

Synonyms:[Ru(C(CCPh)=CHPh)(CO)(PPh₃)2(piperazine dithiocarbamate)]Cl

Chemical Property of [Ru(C(CCPh)=CHPh)(CO)(PPh₃)2(piperazine dithiocarbamate)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [Ru(C(CCPh)=CHPh)(CO)(PPh₃)2(piperazine dithiocarbamate)]Cl

There total 2 articles about [Ru(C(CCPh)=CHPh)(CO)(PPh₃)2(piperazine dithiocarbamate)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

piperazine-1-carbodithioic acid (99-00-3) + [Ru(C(CCPh)CHPh)Cl(CO)(triphenylphosphine)2] → [Ru(C(CCPh)=CHPh)(CO)(PPh3)2(piperazine dithiocarbamate)]Cl (1092555-74-2)

Guidance literature:

In methanol; dichloromethane; S2CNC4H8NH2 dissolved in MeOH; Ru complex in CH2Cl2 added; stirred at room temp. for 3 h; volatiles removed; dissolved in small amt. of CH2Cl2; EtOH added; concd.slowly under reduced pressure; filtered; ppt. washed with hexane; dried under vac.; elem. anal.;

DOI:10.1021/om800686f

Reference yield:

piperazine-1-carbodithioic acid (99-00-3) + Ru(C(C≡CPh)=CHPh)Cl(CO)(PPh3)2 → [Ru(C(CCPh)=CHPh)(CO)(PPh3)2(piperazine dithiocarbamate)]Cl (1092555-74-2)

Guidance literature:

In methanol; dichloromethane; S2CNC4H8NH2 dissolved in MeOH; Ru complex in CH2Cl2 added; stirred at room temp. for 3 h; volatiles removed; dissolved in small amt. of CH2Cl2; EtOH added; concd.slowly under reduced pressure; filtered; ppt. washed with hexane; dried under vac.; elem. anal.;

DOI:10.1021/om800686f

Reference yield: 84.0%

carbon disulfide (75-15-0,12122-00-8) + [Ru(C(CCPh)=CHPh)(CO)(PPh3)2(piperazine dithiocarbamate)]Cl (1092555-74-2) + [Os(CHCH-ferrocenyl)Cl(CO)(2,1,3-benzothiadiazole)(PPh3)2] → Ru(C(C2C6H5)CHC6H5)(CO)(P(C6H5)3)2(S2CNC4H8NCS2)Os(CHCHC5H4FeC5H5)(CO)(P(C6H5)3)2

Guidance literature:

With Et₃N; In dichloromethane; soln. of Ru complex in CH2Cl2 treated with Et3N (excess) and CS2 (excess); stirred for 5 min; Os-Fe complex in CH2Cl2 added; stirred for 2 h; filtered (diatomaceous earth); EtOH added; concd. under reduced pressure; filtered; ppt. washed with hexane; dried under vac.; elem. anal.;

DOI:10.1021/om800686f

upstream raw materials:

piperazine-1-carbodithioic acid

Refernces