Methyl N-phenylformimidate

Base Information

• Chemical Name: Methyl N-phenylformimidate
• CAS No.: 36169-82-1
• Molecular Formula: C8H9 N O
• Molecular Weight: 135.166
• Hs Code.: 2925290090
• DSSTox Substance ID: DTXSID10493207
• Mol file: 36169-82-1.mol

Synonyms:36169-82-1;methyl phenylimidoformate;METHYL N-PHENYLFORMIMIDATE;methyl N-phenylmethanimidate;methyl N-phenylcarboximidate;METHYLN-PHENYLFORMIMIDATE;Methyl phenylmethanimidate;(E)-methyl N-phenylformimidate;methyl (E)-N-phenylformimidate;SCHEMBL10764570;SCHEMBL10764572;DTXSID10493207;AKOS006273074;CS-0301797;EN300-234239;F2147-0919

Chemical Property of Methyl N-phenylformimidate

Chemical Property:

• PSA: 21.59000
• LogP: 1.99280
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 135.068413911
• Heavy Atom Count: 10
• Complexity: 106

Purity/Quality:

99% ^*data from raw suppliers

METHYL-N-PHENYLFORMIMIDATE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC=NC1=CC=CC=C1
• Uses: Methyl phenylimidoformate is used as a reactant in the preparation of N-phenylformimidic esters involving transesterification.

Technology Process of Methyl N-phenylformimidate

There total 5 articles about Methyl N-phenylformimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Formanilid (103-70-8) + methyl iodide (74-88-4) → N-phenyl-formimidic acid methyl ester (36169-82-1) + N,N'-diphenylformamidine (864131-95-3) + N-methyl-N-phenylformamide (93-61-8)

Guidance literature:

wird nach dem Verduennen mit Aether noch ca. 2 Stdn_. gekocht;

DOI:10.1038/sj.bdj.4800483a

Reference yield:

aniline (62-53-3) + trimethyl orthoformate (149-73-5) → N-phenyl-formimidic acid methyl ester (36169-82-1)

Guidance literature:

With aniline hydrochloride; unter Entfernen des entstehenden Methanols;

DOI:10.1021/ja01619a036

Reference yield:

Formanilid (103-70-8) + methyl iodide (74-88-4) → N-phenyl-formimidic acid methyl ester (36169-82-1)

Guidance literature:

With silver(l) oxide; anschliessend Versetzen mit Aether und nachfolgendes 2-stdg. Erhitzen;

DOI:10.1038/sj.bdj.4800483a

upstream raw materials:

aniline

trimethyl orthoformate

diethyl ether

formanilide; silver (I)-compound

Downstream raw materials:

1,3-dimethyl-5-phenylaminomethylenepyrimidine-2,4,6-(1H,3H,5H)-trione

N-cyano-N'-phenyl-formamidine

N,N''-diphenyl-formamidrazone

N-benzyl-N'-phenyl-formamidine