1-Ethyl-3-methylimidazolium Iodide

Base Information

• Chemical Name: 1-Ethyl-3-methylimidazolium Iodide
• CAS No.: 35935-34-3
• Molecular Formula: C6H11IN2
• Molecular Weight: 238.071
• Hs Code.: 29332900
• DSSTox Substance ID: DTXSID5049281
• ChEMBL ID: CHEMBL3186186
• Mol file: 35935-34-3.mol

Synonyms:1-Ethyl-3-methylimidazolium Iodide;35935-34-3;1-ethyl-3-methyl-1H-imidazol-3-ium iodide;1-ethyl-3-methylimidazol-3-ium;iodide;1-Ethyl-3-methyl-3-imidazolium Iodide;DTXSID5049281;MFCD03701101;SCHEMBL379672;C6H11IN2;CHEMBL3186186;DTXCID0029137;IKQCDTXBZKMPBB-UHFFFAOYSA-M;Tox21_202643;AKOS015833267;AKOS030228185;CS-W016763;NCGC00260191-01;1-ethyl-3-methyl imidazolium iodide salt;AS-46677;SY041801;1-Ethyl-3-methylimidazolium iodide, 97%;CAS-35935-34-3;E0556;FT-0696614;E10138;A874498;Q-102700

Chemical Property of 1-Ethyl-3-methylimidazolium Iodide

Chemical Property:

• Melting Point: 79 °C
• PSA: 8.81000
• LogP: -2.66350
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in water, , dichloromethane, ethanol, acetonitrile.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 237.99670
• Heavy Atom Count: 9
• Complexity: 72.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Ethyl-3-methylimidazolium Iodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-41-37/38
• Safety Statements: 26-36-39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN1C=C[N+](=C1)C.[I-]
• Uses: It is used as OLED materials. EMImI reacts with aluminum chloride to form 1-ethyl-3-methylimidazolium halogenoaluminate ionic liquid, [emim]I–(AlCl3)x, which is an excellent solvent for Friedel–Crafts acylation of ferrocene.

Technology Process of 1-Ethyl-3-methylimidazolium Iodide

There total 3 articles about 1-Ethyl-3-methylimidazolium Iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-methyl-1H-imidazole (616-47-7) + ethyl iodide (75-03-6) → 1-ethyl-3-methylimidazolium iodide (35935-34-3)

Guidance literature:

In tetrahydrofuran; for 4h; Heating;

DOI:10.1039/a806708b

Reference yield:

N-Ethylimidazole (7098-07-9) + methyl iodide (74-88-4) → 1-ethyl-3-methylimidazolium iodide (35935-34-3)

Guidance literature:

With diethyl ether;

Reference yield:

→ 1-ethyl-3-methylimidazolium iodide (35935-34-3)

Guidance literature:

upstream raw materials:

1-methyl-1H-imidazole

ethyl iodide

N-Ethylimidazole

methyl iodide

Downstream raw materials:

1-ethyl-3-methylimidazolium 4-hydroxybenzoate

1-ethyl-3-methylimidazolium hexafluorophosphate

1-ethyl-3-methylimidazolium hydroxide

1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Refernces

• 1、 Avent, Anthony G.,Chaloner, Penelope A.,Day, Martin P.,Seddon, Kenneth R.,Welton, Thomas. "Evidence for Hydrogen Bonding in Solution of 1-Ethyl-3-methylimidazolium Halides, and its Implications for Room-temperature Halogenoaluminate(III) Ionic Ligands". . p. 3405 - 3414. Retrieved 1994.
• 2、 Deetlefs, Maggel,Seddon, Kenneth R.,Shara, Michael. "Neoteric optical media for refractive index determination of gems and minerals". . p. 317 - 326. Retrieved 2006.
• 3、 Assenine, Mohammed Amin,Brandán, Silvia Antonia,Bresson, Serge,Haddad, Boumediene,Paolone, Annalisa,Villemin, Didier. "Bidentate cation-anion coordination in the ionic liquid 1-ethyl-3-methylimidazolium hexafluorophosphate supported by vibrational spectra and NBO, AIM and SQMFF calculations". . . Retrieved 2020/04/08.
• 4、 Chen, Kai,Chen, Xiao-Qing,Hu, Yuan-Zhuo,Xia, Peng-Ju,Xiang, Hao-Yue,Xiao, Jun-An,Yang, Hua,Ye, Zhi-Peng. "Photocatalytic C-F Bond Borylation of Polyfluoroarenes with NHC-boranes". supporting information. p. 1742 - 1747. Retrieved 2020/03/24.