benzhydryl-octyl sulfide

Base Information

• Chemical Name: benzhydryl-octyl sulfide
• CAS No.: 102445-61-4
• Molecular Formula: C₂₁H₂₈S
• Molecular Weight: 312.519
• Mol file: 102445-61-4.mol

Synonyms:benzhydryl-octyl sulfide

Chemical Property of benzhydryl-octyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of benzhydryl-octyl sulfide

There total 2 articles about benzhydryl-octyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1,1-Diphenylmethanol (91-01-0) + Octanethiol (111-88-6) → benzhydryl-octyl sulfide (102445-61-4)

Guidance literature:

aluminium dodecatungsten phosphate; In dichloromethane; at 20 ℃; for 16h;

DOI:10.1016/j.tetlet.2005.02.071

Reference yield: 61.0%

1,1-Diphenylmethanol (91-01-0) + Octanethiol (111-88-6) → benzhydryl ether (574-42-5) + benzhydryl-octyl sulfide (102445-61-4)

Guidance literature:

With triethylamine methanesulfonic acid; at 80 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1016/j.tetlet.2012.02.011

Reference yield:

benzhydryl-octyl sulfide (102445-61-4) → dioctyl disulfide (822-27-5)

Guidance literature:

With iodine; In dichloromethane; Heating;

DOI:10.1016/j.tetlet.2005.02.071

upstream raw materials:

1,1-Diphenylmethanol

Octanethiol

Downstream raw materials:

dioctyl disulfide

Refernces

• 1、 Altimari, Jarrad M.,Delaney, Joshua P.,Servinis, Linden,Squire, Jennifer S.,Thornton, Megan T.,Khosa, Simren K.,Long, Benjamin M.,Johnstone, Mark D.,Fleming, Cassandra L.,Pfeffer, Frederick M.,Hickey, Shane M.,Wride, Matthew P.,Ashton, Trent D.,Fox, Bronwyn L.,Byrne, Nolene,Henderson, Luke C.. "Rapid formation of diphenylmethyl ethers and thioethers using microwave irradiation and protic ionic liquids". supporting information; experimental part. p. 2035 - 2039. Retrieved 2012/07/17.