3,3'-(1,4-phenylene)dipropanal

Base Information

• Chemical Name: 3,3'-(1,4-phenylene)dipropanal
• CAS No.: 107399-42-8
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.242
• Mol file: 107399-42-8.mol

Synonyms:3,3'-(1,4-phenylene)dipropanal

Chemical Property of 3,3'-(1,4-phenylene)dipropanal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,3'-(1,4-phenylene)dipropanal

There total 8 articles about 3,3'-(1,4-phenylene)dipropanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

3-(4-(3-hydroxypropyl)phenyl)propanal → 3,3'-(1,4-phenylene)dipropanal (107399-42-8)

Guidance literature:

With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dimethyl sulfoxide; at 20 ℃; for 5h; stereoselective reaction;

DOI:10.1039/c5cc10093c

Reference yield: 55.0%

1,4-bromoiodobenzene (589-87-7) + allyl alcohol (107-18-6) → 3,3'-(1,4-phenylene)dipropanal (107399-42-8) + 4-(4-bromophenyl)bromobenzene (92-86-4) + 2-(4-bromophenyl)propanal (40460-91-1) + 2-[4-(3-oxopropyl)phenyl]propanal + 3-(4-bromophenyl)propanal (80793-25-5)

Guidance literature:

With PdCl₂/PVP-K₃₀; sodium acetate; In N,N-dimethyl-formamide; at 85 ℃; for 3h; Reagent/catalyst; Time; Inert atmosphere;

DOI:10.1016/j.tet.2017.03.034

Reference yield: 54.0%

para-diiodobenzene (624-38-4,1032416-46-8) + allyl alcohol (107-18-6) → 3,3'-(1,4-phenylene)dipropanal (107399-42-8)

Guidance literature:

With tetrabutyl ammonium fluoride; palladium diacetate; sodium hydrogencarbonate; In N,N-dimethyl-formamide; at 50 ℃; for 5h;

DOI:10.1002/ejoc.201701197

upstream raw materials:

3-[4-(2-ethoxycarbonyl-ethyl)-phenyl]-propionic acid ethyl ester

3-(p-iodophenyl)-propanol

para-diiodobenzene

allyl alcohol

Downstream raw materials:

1,4-bis(2-formylethenyl)benzene

3,3'-(1,4-phenylene)dipropanenitrile

Refernces

• 1、 Tarnowicz, Stanis?awa,Alsalahi, Waleed,Mieczyńska, Ewa,Trzeciak, Anna M.. "Heck arylation of allyl alcohol catalyzed by Pd(0) nanoparticles". . p. 5605 - 5612. Retrieved 2017/08/26.
• 2、 -. "Quaternary ammonium compounds having muscle relaxation activity". . . Retrieved 2008/06/13.