Magnesium bromide 2-phenylethan-1-ide (1/1/1)

Base Information

• Chemical Name: Magnesium bromide 2-phenylethan-1-ide (1/1/1)
• CAS No.: 3277-89-2
• Molecular Formula: C8H9 Br Mg
• Molecular Weight: 209.368
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID00446444
• Mol file: 3277-89-2.mol

Synonyms:Magnesium bromide 2-phenylethan-1-ide (1/1/1);magnesium;ethylbenzene;bromide;DTXSID00446444

Chemical Property of Magnesium bromide 2-phenylethan-1-ide (1/1/1)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.04230
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 207.97380
• Heavy Atom Count: 10
• Complexity: 51.1

Purity/Quality:

99% ^*data from raw suppliers

Phenethylmagnesiumbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2-]CC1=CC=CC=C1.[Mg+2].[Br-]

Technology Process of Magnesium bromide 2-phenylethan-1-ide (1/1/1)

There total 2 articles about Magnesium bromide 2-phenylethan-1-ide (1/1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

magnesium (7439-95-4) + 1-phenyl-2-bromoethane (103-63-9) → phenethylmagnesium bromide (3277-89-2)

Guidance literature:

Reference yield:

→ phenethylmagnesium bromide (3277-89-2)

Guidance literature:

DOI:10.1016/S0022-328X(00)88041-9

Reference yield: 88.0%

phenethylmagnesium bromide (3277-89-2) + lithium dimethylacetate (25179-23-1) → 4-methyl-1-phenylpentan-3-one (40463-09-0)

Guidance literature:

With Grignard reagent; N,N-diphenyl-p-methoxyphenylchloromethyleniminium chloride; copper(l) iodide; In tetrahydrofuran; dichloromethane; 1) -30 deg C, 1 h, 2) 0 deg C, 1 h;

DOI:10.1016/S0040-4039(00)85572-0

upstream raw materials:

magnesium

1-phenyl-2-bromoethane

Downstream raw materials:

3-chloro-2-phenethyl-tetrahydro-furan

3-chloro-2-phenethyl-tetrahydro-pyran

2-(1-hydroxy-3-phenylpropyl)-furan

(+/-)-3,4-dimethyl-1-phenylpentan-3-ol

Refernces