1-Iodo-2-phenoxybenzene

Base Information

• Chemical Name: 1-Iodo-2-phenoxybenzene
• CAS No.: 34883-46-0
• Molecular Formula: C12H9 I O
• Molecular Weight: 296.107
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID10512386
• Nikkaji Number: J892.635B
• Wikidata: Q72483583
• Mol file: 34883-46-0.mol

Synonyms:1-Iodo-2-phenoxybenzene;34883-46-0;1-Iodo-2-phenoxy-benzene;MFCD00767196;1-(2-iodophenoxy)benzene;SCHEMBL1869607;DTXSID10512386;AKOS015964732;DS-7032;AC-21016;SY121481;CS-0060560;W17299

Chemical Property of 1-Iodo-2-phenoxybenzene

Chemical Property:

• Vapor Pressure: 0.00163mmHg at 25°C
• Melting Point: 56℃
• Refractive Index: 1.639
• Boiling Point: 303.9°C at 760 mmHg
• Flash Point: 137.6°C
• PSA: 9.23000
• Density: 1.626g/cm³
• LogP: 4.08350
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 295.96981
• Heavy Atom Count: 14
• Complexity: 166

Purity/Quality:

98%Min ^*data from raw suppliers

1-Iodo-2-phenoxybenzene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OC2=CC=CC=C2I

Technology Process of 1-Iodo-2-phenoxybenzene

There total 21 articles about 1-Iodo-2-phenoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-phenoxyaniline (2688-84-8) → 1-(2-iodophenoxy)benzene (34883-46-0)

Guidance literature:

With toluene-4-sulfonic acid; potassium iodide; sodium nitrite; In water; acetonitrile; at 20 ℃; for 0.75h;

DOI:10.1002/chem.201402961

Reference yield: 98.0%

1,2-Diiodobenzene (615-42-9) + phenol (108-95-2,27073-41-2) → 1-(2-iodophenoxy)benzene (34883-46-0)

Guidance literature:

phenol; With sodium hydride; In tetrahydrofuran; N,N-dimethyl acetamide; mineral oil; at 20 ℃; for 0.166667h;

1,2-Diiodobenzene; In tetrahydrofuran; N,N-dimethyl acetamide; mineral oil; at 20 ℃; for 0.5h;

Reference yield: 94.0%

phenyl(2-(((trifluoromethyl)sulfonyl)oxy)phenyl)iodonium trifluoromethanesulfonate → 1-(2-iodophenoxy)benzene (34883-46-0)

Guidance literature:

With caesium carbonate; In acetonitrile; at 25 ℃; for 12h; Schlenk technique;

DOI:10.1002/anie.201806405

upstream raw materials:

2-phenoxyaniline

diphenylether

2-Iodophenol

diphenyliodonium bromide

Downstream raw materials:

2'-nitro-2-phenoxybiphenyl

2,2'-diphenoxybiphenyl

3-phenoxyaniline

2,7-dibromo-9-(2-phenoxyphenyl)-9-fluorenol

Refernces

• 1、 -. "COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME". Paragraph 0080-0082. . Retrieved 2019/04/14.
• 2、 -. "COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME". Paragraph 0087; 0093-0095. . Retrieved 2018/06/15.