1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether

Base Information

• Chemical Name: 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether
• CAS No.: 343942-17-6
• Molecular Formula: C₁₀H₁₅NO₃
• Molecular Weight: 197.234
• Mol file: 343942-17-6.mol

Synonyms:1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether

Chemical Property of 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether

There total 3 articles about 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

methanol (67-56-1) + 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl acetate (67609-55-6) → 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether (343942-17-6) + 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether (79744-70-0)

Guidance literature:

With sulfuric acid; at 35 ℃; for 0.5h; Product distribution; other acids, concentrations and temperatures;

Reference yield:

1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl acetate (67609-55-6) → 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether (343942-17-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / aluminum hydride / tetrahydrofuran / 0.25 h / -20 °C

2: 260 mg / silver oxide, potassium hydroxyde / 6 h / Ambient temperature

With aluminium hydride; potassium hydroxide; silver(l) oxide; In tetrahydrofuran;

Reference yield:

1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienol (79744-67-5) + methyl iodide (74-88-4) → 1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl methyl ether (343942-17-6)

Guidance literature:

With potassium hydroxide; silver(l) oxide; for 6h; Ambient temperature;

upstream raw materials:

methanol

1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienyl acetate

1-ethyl-4-methyl-4-nitrocyclohexa-2,5-dienol

methyl iodide

Downstream raw materials:

2-methyl,5-ethyl-phenol

5-ethyl-2-methylphenyl methyl ether

2-ethyl-4-methylphenyl methyl ether

Refernces