limonene hydroperoxide

Base Information

• Chemical Name: limonene hydroperoxide
• CAS No.: 1199-39-9
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.236
• Mol file: 1199-39-9.mol

Synonyms:limonene hydroperoxide

Chemical Property of limonene hydroperoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of limonene hydroperoxide

There total 4 articles about limonene hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

D-limonene (5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3) → Limonene oxide (1195-92-2) + Carvone (99-49-0,22327-39-5) + limonene hydroperoxide (1199-39-9) + L-perillaldehyde (5503-12-8)

Guidance literature:

With tert.-butylhydroperoxide; 2,6-di-tert-butyl-4-methyl-phenol; In water; acetonitrile; at 69.84 ℃; for 5h; Inert atmosphere;

DOI:10.1016/j.mcat.2018.11.005

Reference yield:

D-limonene (5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3) → Limonene oxide (1195-92-2) + Carvone (99-49-0,22327-39-5) + 5-Isopropenyl-2-methyl-cyclohex-2-enol (99-48-9,22567-18-6,20307-86-2) + limonene hydroperoxide (1199-39-9) + L-perillaldehyde (5503-12-8)

Guidance literature:

With tert.-butylhydroperoxide; In water; acetonitrile; at 69.84 ℃; for 5h; Inert atmosphere;

DOI:10.1016/j.mcat.2018.11.005

Reference yield:

D-limonene (5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3) → Limonene oxide (1195-92-2) + Carvone (99-49-0,22327-39-5) + 5-Isopropenyl-2-methyl-cyclohex-2-enol (99-48-9,22567-18-6,20307-86-2) + limonene hydroperoxide (1199-39-9) + L-perillaldehyde (5503-12-8) + 1-methyl-4-(1-methylethenyl)-cyclohexane-1,2-diol (13833-08-4,38630-75-0,39067-95-3,39903-99-6,39904-01-3,39904-04-6,39904-09-1,39904-12-6,57457-97-3,59121-74-3,59121-75-4,59121-76-5,59121-77-6,59121-82-3,76740-41-5,1946-00-5)

Guidance literature:

With dihydrogen peroxide; In water; acetonitrile; at 69.84 ℃; for 5h; Inert atmosphere;

DOI:10.1016/j.mcat.2018.11.005

upstream raw materials:

C₁₀H₁₅Br

D-limonene

Refernces

• 1、 Vaschetti, Virginia M.,Cánepa, Analía L.,Barrera, Deicy,Sapag, Karim,Eimer, Griselda A.,Casuscelli, Sandra G.. "Limonene oxyfunctionalization over Cu-modified silicates employing hydrogen peroxide and t-Butyl hydroperoxide: Reaction pathway analysis". . . Retrieved 2018/11/23.