Sulfoxide, methyl tetradecyl

Base Information

• Chemical Name: Sulfoxide, methyl tetradecyl
• CAS No.: 3079-31-0
• Molecular Formula: C₁₅H₃₂OS
• Molecular Weight: 260.484
• DSSTox Substance ID: DTXSID301308171
• Nikkaji Number: J103.424C
• ChEMBL ID: CHEMBL172099
• Mol file: 3079-31-0.mol

Synonyms:Sulfoxide, methyl tetradecyl;1-Methanesulfinyl-tetradecane;CHEMBL172099;Tetradecane, 1-(methylsulfinyl)-;3079-31-0;Methyltetradecyl sulfoxide;SCHEMBL29320;1-(Methylsulfinyl)tetradecane;1-(Methylsulfinyl)tetradecane #;DTXSID301308171;BDBM50224822

Chemical Property of Sulfoxide, methyl tetradecyl

Chemical Property:

• Boiling Point: 385.6±11.0 °C(Predicted)
• PSA: 36.28000
• Density: 0.911±0.06 g/cm3(Predicted)
• LogP: 5.93170
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 260.21738681
• Heavy Atom Count: 17
• Complexity: 168

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCS(=O)C

Technology Process of Sulfoxide, methyl tetradecyl

There total 2 articles about Sulfoxide, methyl tetradecyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methyl n-tetradecyl sulfide (7289-45-4) → methyl n-tetradecyl sulfoxide (3079-31-0)

Guidance literature:

With sodium periodate; tetrabutylammomium bromide; In methanol; at 20 - 24 ℃; for 24h;

DOI:10.1080/00304940009356286

Reference yield:

myristyl chloride (2425-54-9) → methyl n-tetradecyl sulfoxide (3079-31-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 92 percent / aq. ethanol / Heating

2: 96 percent / NaIO₄; tetrabutylammonium bromide / methanol / 24 h / 20 - 24 °C

With sodium periodate; tetrabutylammomium bromide; In methanol; ethanol; 1: Substitution / 2: Oxidation;

DOI:10.1080/00304940009356286

upstream raw materials:

methyl n-tetradecyl sulfide

myristyl chloride

Refernces

• 1、 Yamamoto, Tamotsu,Hayakawa, Tetsushi,Yoshino, Mugi,Hata, Soh-Ichiroh,Hirayama, Yorinobu. "An efficient oxidation of long chain alkyl methyl sulfides to sulfoxides". . p. 192 - 196. Retrieved 2007/10/03.