POLY(2 5-BIS(1 4 7 10-TETRAOXAUNDECYL)-&

Base Information

• Chemical Name: POLY(2 5-BIS(1 4 7 10-TETRAOXAUNDECYL)-&
• CAS No.: 221244-49-1
• Molecular Formula: C₁₃₄H₁₂₆Cl₂O₁₀P₆Ru₂
• Molecular Weight: 2355.36
• Mol file: 221244-49-1.mol

Synonyms:POLY(2 5-BIS(1 4 7 10-TETRAOXAUNDECYL)-&;btem-ppv;BTEM-PPV, Poly[2,5-bis(triethoxymethoxy)-1,4-phenylene vinylene], Poly(2,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-1,4-phenylenevinylene)

Chemical Property of POLY(2 5-BIS(1 4 7 10-TETRAOXAUNDECYL)-&

Chemical Property:

Purity/Quality:

98%,99%, ^*data from raw suppliers

Poly(2,5-bis(1,4,7,10-tetraoxaundecyl)-1,4-phenylenevinylene) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: BTEM-PPV is a conjugating polymer that can be used in the fabrication of red-light emitting electrochemical cells (LECs). These LECs can potentially be used in the formation of novel chemical sensor systems and organic light emitting diodes (OLEDs).

Technology Process of POLY(2 5-BIS(1 4 7 10-TETRAOXAUNDECYL)-&

There total 2 articles about POLY(2 5-BIS(1 4 7 10-TETRAOXAUNDECYL)-& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

[{(PPh3)2(CO)ClRu}2(μ-HC=CH-(C6H2)((O(CH2)2)3OCH3)-CH=CH)] (221244-49-1) + trimethylphosphane (594-09-2) → C44H90Cl2O10P6Ru2 (1566572-04-0,221244-49-1)

Guidance literature:

In tetrahydrofuran; dichloromethane; at 20 ℃; for 20h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt52677a

Reference yield:

1,4-bis((triethylene glycol monomethyl ether)oxy)-2,5-diethylnylbenzene (444823-79-4) + (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) → [{(PPh3)2(CO)ClRu}2(μ-HC=CH-(C6H2)((O(CH2)2)3OCH3)-CH=CH)] (221244-49-1)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt52677a

Reference yield: 39.0%

[{(PPh3)2(CO)ClRu}2(μ-HC=CH-(C6H2)((O(CH2)2)3OCH3)-CH=CH)] (221244-49-1) + trimethylphosphane (594-09-2) → C44H90Cl2O10P6Ru2 (1566572-04-0,221244-49-1)

Guidance literature:

In tetrahydrofuran; dichloromethane; at 20 ℃; for 20h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt52677a

upstream raw materials:

trimethylphosphane

1,4-bis((triethylene glycol monomethyl ether)oxy)-2,5-diethylnylbenzene

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

C₄₄H₉₀Cl₂O₁₀P₆Ru₂

Refernces