Glycolate

Base Information

• Chemical Name: Glycolate
• CAS No.: 666-14-8
• Molecular Formula: C₂H₃O₃
• Molecular Weight: 75.044
• DSSTox Substance ID: DTXSID901036536
• Nikkaji Number: J816.702H
• Wikidata: Q27104089
• Mol file: 666-14-8.mol

Synonyms:glycolate;glycolic acid;glycolic acid, 1-(14)C-labeled;glycolic acid, 2-(14)C-labeled;glycolic acid, calcium salt;glycolic acid, monoammonium salt;glycolic acid, monolithium salt;glycolic acid, monopotassium salt;glycolic acid, monosodium salt;glycolic acid, potassium salt;hydroxyacetic acid;potassium glycolate

Chemical Property of Glycolate

Chemical Property:

• XLogP3: -0.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 75.008218953
• Heavy Atom Count: 5
• Complexity: 34.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C(=O)[O-])O

Technology Process of Glycolate

There total 20 articles about Glycolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylene glycol (107-21-1) → formate (71-47-6) + hydrogen (1333-74-0) + glycolate (666-14-8)

Guidance literature:

With water; potassium hydroxide; at 60 ℃; Electrolysis;

DOI:10.1016/j.ica.2021.120245

Reference yield:

1-benzyl-3-methylimidazolium chloride (36443-80-8) → formate (71-47-6) + glycolate (666-14-8) + methylamine (74-89-5) + benzylamine (100-46-9)

Guidance literature:

With potassium hydroxide; In water; at 60 ℃; for 264h; Temperature;

DOI:10.1021/acs.joc.9b02493

Reference yield:

1-benzyl-2,3-dimethylimidazolium chloride (36443-79-5) → formate (71-47-6) + acetate (71-50-1) + glycolate (666-14-8) + methylamine (74-89-5) + benzylamine (100-46-9)

Guidance literature:

With potassium hydroxide; In water; at 60 ℃; for 456h; Temperature;

DOI:10.1021/acs.joc.9b02493

upstream raw materials:

glycolic Acid

monofluoroacetate

Methoxyacetone

1,1-Dichloroacetone

Refernces

• 1、 Bellini, Marco,Pagliaro, Maria V.,Marchionni, Andrea,Filippi, Jonathan,Miller, Hamish A.,Bevilacqua, Manuela,Lavacchi, Alessandro,Oberhauser, Werner,Mahmoudian, Jafar,Innocenti, Massimo,Fornasiero, Paolo,Vizza, Francesco. "Hydrogen and chemicals from alcohols through electrochemical reforming by Pd-CeO2/C electrocatalyst". . . Retrieved 2021/01/25.
• 2、 Geraldes, Adriana N.,Silva, Dionisio F.,Silva, Ju?lio C.M.,Souza, Rodrigo F.B.,Spinace?, Estevam V.,Neto, Almir O.,Linardi, Marcelo,Santos, Mauro C.. "Glycerol electrooxidation in alkaline medium using Pd/c, Au/c and Pdau/c electrocatalysts prepared by electron beam irradiation". . p. 831 - 840. Retrieved 2014/06/24.