C₂₂H₂₂O₆

Base Information

• Chemical Name: C₂₂H₂₂O₆
• CAS No.: 259670-55-8
• Molecular Formula: C₂₂H₂₂O₆
• Molecular Weight: 382.413
• Mol file: 259670-55-8.mol

Synonyms:C₂₂H₂₂O₆

Chemical Property of C₂₂H₂₂O₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₂H₂₂O₆

There total 5 articles about C₂₂H₂₂O₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

meso-3,4-dibenzoyloxy-8-oxabicyclo[4.3.0]nonane (259670-51-4) → C22H22O6 (259670-55-8) + C22H22O6

Guidance literature:

With iodosylbenzene; (R,R)-(salen)manganese(III); In chlorobenzene; at -30 ℃; for 72h; Title compound not separated from byproducts;

DOI:10.3987/com-99-s20

Reference yield:

cis-8-oxabicyclo<4.3.0>non-3-ene (3470-42-6,3471-41-8,4743-55-9,56000-18-1) → C22H22O6 (259670-55-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 63 percent / DABCO; K₃Fe(CN)6; K₂CO₃ / K₂OsO₄*2H₂O

2: 72 percent / Et₃N; DMAP

3: iodosylbenzene / (R,R)-(salen)manganese(III) complex / chlorobenzene / 72 h / -30 °C

With 1,4-diaza-bicyclo[2.2.2]octane; dmap; iodosylbenzene; potassium carbonate; triethylamine; potassium hexacyanoferrate(III); potassium osmate(VI); (R,R)-(salen)manganese(III); In chlorobenzene; 1: Oxidation / 2: Acylation / 3: Oxidation;

DOI:10.3987/com-99-s20

Reference yield:

cis-1,6-dihydroxymethyl-3-cyclohexene (439919-46-7) → C22H22O6 (259670-55-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 100 percent / dimethylsulfoxide / 180 °C

2: 63 percent / DABCO; K₃Fe(CN)6; K₂CO₃ / K₂OsO₄*2H₂O

3: 72 percent / Et₃N; DMAP

4: iodosylbenzene / (R,R)-(salen)manganese(III) complex / chlorobenzene / 72 h / -30 °C

With 1,4-diaza-bicyclo[2.2.2]octane; dmap; iodosylbenzene; potassium carbonate; triethylamine; potassium hexacyanoferrate(III); potassium osmate(VI); (R,R)-(salen)manganese(III); In dimethyl sulfoxide; chlorobenzene; 1: Dehydration / 2: Oxidation / 3: Acylation / 4: Oxidation;

DOI:10.3987/com-99-s20

upstream raw materials:

meso-3,4-dibenzoyloxy-8-oxabicyclo[4.3.0]nonane

cis-8-oxabicyclo<4.3.0>non-3-ene

cis-1,6-dihydroxymethyl-3-cyclohexene

(3ar,7ac)-octahydro-isobenzofuran-5c,6c-diol

Downstream raw materials:

C₂₂H₂₀O₆

Refernces