NAPHTHALENE-13C10

Base Information

• Chemical Name: NAPHTHALENE-13C10
• CAS No.: 219526-41-7
• Molecular Formula: C₁₀H₈
• Molecular Weight: 138.064
• Mol file: 219526-41-7.mol

Synonyms:NAPHTHALENE-13C10;Naphthalene-ul-13C

Chemical Property of NAPHTHALENE-13C10

Chemical Property:

• Melting Point: 80-82 °C(lit.)
• Boiling Point: 218 °C(lit.)
• PSA: 0.00000
• LogP: 2.83980

Purity/Quality:

95% ^*data from raw suppliers

Naphthalene-13C10 ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N
• Statements: 22-40-50/53
• Safety Statements: 36/37-46-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of NAPHTHALENE-13C10

There total 7 articles about NAPHTHALENE-13C10 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

3,4-dihydronaphthalen-1(2H)-one-13C10 (1323432-59-2,189811-58-3) → U-(13)C-naphthalene (219526-41-7,287399-39-7)

Guidance literature:

With diethylsulfone; potassium tert-butylate; In N,N-dimethyl acetamide; at 150 ℃; Inert atmosphere;

DOI:10.1039/c0ob01107j

Reference yield:

[13C]methanol (14742-26-8) → 13C7-toluene (287399-36-4,287399-35-3) + U-(13)C-naphthalene (219526-41-7,287399-39-7)

Guidance literature:

With H-GaAl-ZSM-5 zeolite; at 550 ℃;

DOI:10.1002/anie.200500694

Reference yield:

benzene-(13)C6 (32488-44-1) → U-(13)C-naphthalene (219526-41-7,287399-39-7)

Guidance literature:

Multi-step reaction with 4 steps

1.1: aluminum (III) chloride / 1,1,2,2-tetrachloroethane

2.1: hydrazine hydrate / diethylene glycol / 0.5 h / 20 °C

2.2: 120 - 215 °C

3.1: methanesulfonic acid / 0.5 h / 90 °C / Inert atmosphere

4.1: diethylsulfone; potassium tert-butylate / N,N-dimethyl acetamide / 150 °C / Inert atmosphere

With aluminum (III) chloride; methanesulfonic acid; diethylsulfone; potassium tert-butylate; hydrazine hydrate; In N,N-dimethyl acetamide; 1,1,2,2-tetrachloroethane; diethylene glycol; 2.1: Wolff-Kishner reduction / 2.2: Wolff-Kishner reduction;

DOI:10.1039/c0ob01107j

upstream raw materials:

[¹³C]methanol

4-oxo-4-(phenyl-¹³C₆)butanoic-1,2,3,4-¹³C₄ acid

4-(phenyl-¹³C₆)butanoic-1,2,3,4-¹³C₄ acid

3,4-dihydronaphthalen-1(2H)-one-¹³C₁₀

Downstream raw materials:

⁽¹³⁾C₁₈H₁₂O₃

⁽¹³⁾C₁₈H₁₂O₃

Refernces

• 1、 Thilakaratne, Rajeeva,Tessonnier, Jean-Philippe,Brown, Robert C.. "Conversion of methoxy and hydroxyl functionalities of phenolic monomers over zeolites". . p. 2231 - 2239. Retrieved 2016/04/19.
• 2、 Choudhary, Vasant R.,Mondal, Kartick C.,Mulla, Shafeek A. R.. "Simultaneous conversion of methane and methanol into gasoline over bifunctional Ga-, Zn-, In-, and/or Mo-modified ZSM-5 zeolites". . p. 4381 - 4385. Retrieved 2007/10/03.