tetrakis(cyclohexylmethylamide)zirconium

Base Information

• Chemical Name: tetrakis(cyclohexylmethylamide)zirconium
• CAS No.: 610786-42-0
• Molecular Formula: C₂₈H₅₆N₄Zr
• Molecular Weight: 540.003
• Mol file: 610786-42-0.mol

Synonyms:tetrakis(cyclohexylmethylamide)zirconium

Chemical Property of tetrakis(cyclohexylmethylamide)zirconium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of tetrakis(cyclohexylmethylamide)zirconium

There total 1 articles about tetrakis(cyclohexylmethylamide)zirconium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.7%

N-methylcyclohexylamine (100-60-7) + zirconium(IV) chloride (10026-11-6) → tetrakis(cyclohexylmethylamide)zirconium (610786-42-0)

Guidance literature:

With Li-n-Bu; In hexane; toluene; in oxygen and moisture free atmosphere; soln. of ligand in toluene addeddropwise to soln. of Li-n-Bu in hexane; stirred at room temp. for 2.5 h ; ZrCl4 added gradually for 30 min; stirred for 18 h; filtered; filtrate reduced to oil under reduced pressure; elem. anal.;

DOI:10.1021/om030268+

Reference yield: 77.0%

tetrakis(cyclohexylmethylamide)zirconium (610786-42-0) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → zirconium(cyclohexylmethylamide)2[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2 (610786-39-5)

Guidance literature:

In hexane; in oxygen and moisture free atmosphere; ligand (2 equiv.) added gradually to soln. of Zr compd. in hexane at -90°C; stirred for 2.5 h; filtered; filtrate concd.; put in freezer at -31°C; filtered; ppt. washed with cold n-hexane; elem. anal.;

DOI:10.1021/om030268+

Reference yield:

tetrakis(cyclohexylmethylamide)zirconium (610786-42-0) → dichlorozirconium[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2 (610786-41-9)

Guidance literature:

Multi-step reaction with 2 steps

1: hexane

2: diethyl ether

In diethyl ether; hexane;

DOI:10.1021/om030268+

upstream raw materials:

N-methylcyclohexylamine

zirconium(IV) chloride

Downstream raw materials:

zirconium(cyclohexylmethylamide)2[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2

dichlorozirconium[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2

zirconium(pentafluorophenoxide)2[η2-C(N-2,6-dimethylphenyl)N(Me)cyclohexyl]2

Refernces