tert-butyl thiophenoxy nitroxide radical

Base Information

• Chemical Name: tert-butyl thiophenoxy nitroxide radical
• CAS No.: 59504-24-4
• Molecular Formula: C₁₀H₁₄NOS
• Molecular Weight: 196.293
• Mol file: 59504-24-4.mol

Synonyms:tert-butyl thiophenoxy nitroxide radical

Chemical Property of tert-butyl thiophenoxy nitroxide radical

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl thiophenoxy nitroxide radical

There total 3 articles about tert-butyl thiophenoxy nitroxide radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

t-butylnitrite (917-95-3) + phenyl thiobenzoate (884-09-3) → di-tert-butyl nitroxide (2406-25-9,44871-19-4) + benzoyl-tert-butylnitroxyl radical (35822-90-3) + tert-butyl thiophenoxy nitroxide radical (59504-24-4) + C23H24NO2S2 (77839-04-4) + C23H24NO2S2 (77839-03-3)

Guidance literature:

at 25 ℃; Product distribution; Mechanism; Irradiation;

DOI:10.1007/BF00953585

Reference yield:

t-butylnitrite (917-95-3) + (phenylthio)acetic acid (103-04-8) → tert-butyl thiophenoxy nitroxide radical (59504-24-4) + tert-butyl thiophenoxymethyl nitroxide radical

Guidance literature:

With benzophenone; In acetonitrile; Mechanism; Irradiation;

DOI:10.1021/ja00524a063

Reference yield:

benzoic acid phenyl ester (93-99-2) + t-butylnitrite (917-95-3) + diphenyldisulfane (882-33-7) → tert-butyl thiophenoxy nitroxide radical (59504-24-4) + C23H24NO3S + C23H24NO3S (65751-54-4)

Guidance literature:

at -20 ℃; Product distribution; Mechanism; Irradiation;

DOI:10.1007/BF00953585

upstream raw materials:

t-butylnitrite

(phenylthio)acetic acid

phenyl thiobenzoate

benzoic acid phenyl ester

Refernces

• 1、 Novak, Michael,Miller, Audrey,Bruice, Thomas C.,Tollin, Gordon. "The Mechanism of Flavin 4a Substitution Which Accompanies Photolytic Decarboxylation of α-Substituted Acetic Acids. Carbanion vs. Radical Intermediates". . p. 1465 - 1467. Retrieved 2007/10/02.