17-phenyl-16,17-dehydrosparteinium hydroxide

Base Information

• Chemical Name: 17-phenyl-16,17-dehydrosparteinium hydroxide
• CAS No.: 117634-60-3
• Molecular Formula: C₂₁H₂₉N₂*HO
• Molecular Weight: 326.482
• Mol file: 117634-60-3.mol

Synonyms:17-phenyl-16,17-dehydrosparteinium hydroxide

Chemical Property of 17-phenyl-16,17-dehydrosparteinium hydroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 17-phenyl-16,17-dehydrosparteinium hydroxide

There total 3 articles about 17-phenyl-16,17-dehydrosparteinium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lupanine perchlorate (6376-21-2,7400-11-5,14691-01-1,18783-52-3,61740-19-0,76030-37-0) → 17-phenyl-16,17-dehydrosparteinium hydroxide (117634-60-3)

Guidance literature:

Multi-step reaction with 3 steps

1: H₂, / PtO₂, / aq. HCl / 15 h / 1034.3 Torr

2: 60 mg / potassium ferricyanide, 10percent NaOH, / aq. HCl / 0.67 h

3: 1.) ether, reflux, 30 min, 2.) ether, toluene, 100 deg C, 1 h,

With sodium hydroxide; hydrogen; potassium hexacyanoferrate(III); platinum(IV) oxide; In hydrogenchloride;

DOI:10.1139/v88-280

Reference yield:

(-)-l-sparteine (90-39-1,446-95-7,492-06-8,492-08-0,4985-24-4,6838-37-5,6917-37-9,24915-04-6,88269-31-2) → 17-phenyl-16,17-dehydrosparteinium hydroxide (117634-60-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 60 mg / potassium ferricyanide, 10percent NaOH, / aq. HCl / 0.67 h

2: 1.) ether, reflux, 30 min, 2.) ether, toluene, 100 deg C, 1 h,

With sodium hydroxide; potassium hexacyanoferrate(III); In hydrogenchloride;

DOI:10.1139/v88-280

Reference yield:

phenyllithium (591-51-5) + 17-oxosparteine (489-72-5,577-37-7,1218-51-5,6871-54-1,29882-72-2,82109-83-9,131829-31-7) → 17-phenyl-16,17-dehydrosparteinium hydroxide (117634-60-3)

Guidance literature:

Yield given. Multistep reaction; 1.) ether, reflux, 30 min, 2.) ether, toluene, 100 deg C, 1 h,;

DOI:10.1139/v88-280

upstream raw materials:

phenyllithium

17-oxosparteine

lupanine perchlorate

(-)-l-sparteine

Downstream raw materials:

benzoic acid

Refernces