3,3'-Diiodobenzophenone

Base Information

• Chemical Name: 3,3'-Diiodobenzophenone
• CAS No.: 25186-99-6
• Molecular Formula: C13H8I2O
• Molecular Weight: 434.015
• Hs Code.: 2914700090
• DSSTox Substance ID: DTXSID30397894
• Nikkaji Number: J541.097E
• Wikidata: Q72467136
• ChEMBL ID: CHEMBL446014
• Mol file: 25186-99-6.mol

Synonyms:3,3'-Diiodobenzophenone;Bis(3-iodophenyl)methanone;25186-99-6;Methanone, bis(3-iodophenyl)-;3,3-Diiodobenzophenone;3,3'-diiodobenzo-phenone;bis(3-iodanylphenyl)methanone;CHEMBL446014;SCHEMBL3673834;DTXSID30397894;AKOS005173940;AC-22950;AM20040022;FT-0653458;A817688

Chemical Property of 3,3'-Diiodobenzophenone

Chemical Property:

• Melting Point: 147-149 °C
• Boiling Point: 458.2 °C at 760 mmHg
• Flash Point: 230.9 °C
• PSA: 17.07000
• Density: 2.05 g/cm³
• LogP: 4.12680
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 433.86646
• Heavy Atom Count: 16
• Complexity: 230

Purity/Quality:

98%Min ^*data from raw suppliers

Bis(3-iodophenyl)methanone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)I)C(=O)C2=CC(=CC=C2)I

Technology Process of 3,3'-Diiodobenzophenone

There total 5 articles about 3,3'-Diiodobenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

benzophenone (119-61-9) → bis(3-iodophenyl)methanone (25186-99-6)

Guidance literature:

With potassium permanganate; sulfuric acid; iodine; acetic anhydride; In acetic acid; at 35 ℃; for 1h; other reagent;

DOI:10.1246/bcsj.72.115

Reference yield: 45.0%

benzophenone (119-61-9) → 3-iodobenzophenone (25116-37-4) + bis(3-iodophenyl)methanone (25186-99-6)

Guidance literature:

With N-iodo-succinimide; trifluorormethanesulfonic acid; for 2h; Ambient temperature;

DOI:10.1021/jo00063a052

Reference yield:

3,3'-diaminobenzophenone (611-79-0) → bis(3-iodophenyl)methanone (25186-99-6)

Guidance literature:

3,3'-diaminobenzophenone; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃; for 2h; Inert atmosphere;

With sodium iodide; In water; at 25 ℃; for 4h;

upstream raw materials:

benzophenone

3,3'-dinitrobenzophenone

3,3'-diaminobenzophenone

Downstream raw materials:

C₅₃H₅₈O₉

acetic acid bis-(3-iodo-phenyl)-methyl ester

bis-(3-iodo-phenyl)-methanol

Bis-(3-phenylethynyl-phenyl)-methanone

Refernces

• 1、 Moriconi et al.. "". . p. 3928,3930, 3932. Retrieved 1962.
• 2、 Sharmoukh,Ko, Kyoung Chul,Noh, Changho,Lee, Jin Yong,Son, Seung Uk. "Designed synthesis of multi-electrochromic systems bearing diaryl ketone and isophthalates". scheme or table. p. 6708 - 6711. Retrieved 2010/12/19.