2,2'-OXYDIANILINE

Base Information

• Chemical Name: 2,2'-OXYDIANILINE
• CAS No.: 24878-25-9
• Molecular Formula: C12H12N2O
• Molecular Weight: 200.24
• Hs Code.: 2922299090
• Mol file: 24878-25-9.mol

Synonyms:Bis(2-aminophenyl) ether;2,2'-Oxydianiline;Aniline,2,2'-oxydi- (6CI,7CI,8CI);

Chemical Property of 2,2'-OXYDIANILINE

Chemical Property:

• Melting Point: 61-64 °C(lit.)
• Boiling Point: 328.226 °C at 760 mmHg
• PKA: 4.15±0.10(Predicted)
• Flash Point: 163.424 °C
• PSA: 61.27000
• Density: 1.217 g/cm³
• LogP: 3.80570
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Water Solubility.: Slightly soluble in water.

Purity/Quality:

99% ^*data from raw suppliers

2,2''-Oxydianiline ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: It is catalytic reagent and used in pharmaceutical industry.

Technology Process of 2,2'-OXYDIANILINE

There total 13 articles about 2,2'-OXYDIANILINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis(2-nitrophenyl)ether (2217-65-4) → bis(2-aminophenyl)ether (24878-25-9)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 2h;

DOI:10.1021/acs.joc.8b01631

Reference yield: 92.0%

2-nitro-2'-aminobiphenylether (91973-79-4) → bis(2-aminophenyl)ether (24878-25-9)

Guidance literature:

With iron; ammonium chloride; In ethanol; water; for 3h; Inert atmosphere; Reflux;

Reference yield: 89.0%

→ bis(2-aminophenyl)ether (24878-25-9)

Guidance literature:

upstream raw materials:

bis(2-nitrophenyl)ether

2-Chloronitrobenzene

2-hydroxynitrobenzene

diphenylether

Downstream raw materials:

bis-(2-thioureido-phenyl)-ether

2,2′-oxybis(iodobenzene)

2,2'-bis(2-methoxyacetamido)diphenyl ether

tetrabenzo--1,4,11-oxadiazacyclotridecan-5,10-dione

Refernces

• 1、 Mondal, Manas Kumar,Tiwari, Archana,Mukherjee, Chandan. "Solid-state valence tautomeric octahedral {CoII[(BQ-N-Cat)]2}0 complex formation via ligand-centered phenolic C-O bond breaking and Co-O bond making". . p. 11995 - 11998. Retrieved 2016.
• 2、 -. "A silicon-containing compound and comprising the silicon-containing compound of the organic electroluminescent device (by machine translation)". . . Retrieved 2019/04/15.
• 3、 -. "Method for the preparation of diphenyl ether compounds". Paragraph 0050-0052. . Retrieved 2016/12/01.