ethyl tributyltin sulfide

Base Information

• Chemical Name: ethyl tributyltin sulfide
• CAS No.: 23716-85-0
• Molecular Formula: C14H32 S Sn
• Molecular Weight: 351.184
• Hs Code.: 2931900090
• Mol file: 23716-85-0.mol

Synonyms:Ethyltributylstannyl sulfide; Tributyl(ethylthio)stannane; Tributyl(ethylthio)tin;Tributyltin ethylmercaptide

Chemical Property of ethyl tributyltin sulfide

Chemical Property:

• PSA: 38.80000
• Density: 1.127
• LogP: 5.81760

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl tributyltin sulfide

There total 4 articles about ethyl tributyltin sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

phenyl-dithiophosphonous acid diethyl ester (1486-37-9) → tri-n-butyltin(SC2H5) (23716-85-0) + phenylphosphane (638-21-1)

Guidance literature:

With tri-n-butyl-tin hydride; for 120h; Ambient temperature;

Reference yield: 94.0%

phenyl-dithiophosphonous acid diethyl ester (1486-37-9) + tri-n-butyl-tin hydride (688-73-3) → tri-n-butyltin(SC2H5) (23716-85-0) + phenylphosphane (638-21-1)

Guidance literature:

In neat (no solvent); sealed ampul, room temperature, 3d; under Ar: fractionation; mixture of diethyl phenylphosphonodithioite and stannane (no isolation); detn. by 31P NMR;;

Reference yield: 91.0%

ethyl ester of ethylphenylthiophosphinic acid (6587-98-0,62621-04-9,62621-07-2) → tri-n-butyltin(SC2H5) (23716-85-0) + ethylphenylphosphine (3619-88-3)

Guidance literature:

With tri-n-butyl-tin hydride; for 42h; Ambient temperature;

upstream raw materials:

ethyl ester of ethylphenylthiophosphinic acid

phenyl-dithiophosphonous acid diethyl ester

tri-n-butyl-tin hydride

Downstream raw materials:

tri-n-butyl-tin hydride

S-ethyl 2,3,4,6-tetra-O-acetyl-1-deoxy-1-thio-α-D-mannopyranoside

1,3-Dibenzyl-5-ethylsulfanyl-1H-pyrimidine-2,4-dione

Acetic acid (2R,3S,4S,5R,6R)-6-acetoxymethyl-4,5-bis-benzyloxy-2-ethylsulfanyl-tetrahydro-pyran-3-yl ester

Refernces