2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Base Information

• Chemical Name: 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE IRON(III) CHLORIDE
• CAS No.: 28755-93-3
• Molecular Formula: C36H44 Cl Fe N4
• Molecular Weight: 624.072
• Mol file: 28755-93-3.mol

Synonyms:Iron,chloro[2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-5-12)-; Iron, chloro[2,3,7,8,12,13,17,18-octaethylporphinato(2-)]- (8CI);21H,23H-Porphine, 2,3,7,8,12,13,17,18-octaethyl-, iron complex;21H,23H-Porphine, iron deriv.; 2,3,7,8,12,13,17,18-Octaethyl porphine iron(III)chloride; Chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron;Chloro(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III);Chloro(octaethylporphinato)iron; Chloro(octaethylporphyrinato)iron; Ironoctaethylporphyrin chloride; Iron(III) octaethylporphyrin chloride;Octaethylporphyrinatoiron(III) chloride

Chemical Property of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Chemical Property:

• PSA: 34.58000
• LogP: 6.82120

Purity/Quality:

98%,99%, ^*data from raw suppliers

Fe(III)OctaethylporphineChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Fe(III) Octaethylporphine chloride is a synthetic porphyrin used to reduce oxygen and study heme. An iron–porphyrin adlayer adsorbed on the Au(111) substrate was used to study the electrocatalytic reduction of O2 in HClO4.

Technology Process of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE IRON(III) CHLORIDE

There total 13 articles about 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE IRON(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

pyridine (110-86-1) + hydrogenchloride (7647-01-0,15364-23-5) + bis(pyridine)iron(II) octaethylporphyrin (19496-63-0) + oxygen (80937-33-3) → iron(III)octaethylporphyrin chloride (28755-93-3) + octaethylverdohemochrome + [Fe(C19H3O2(C2H5)8N4)]2 (150431-73-5)

Guidance literature:

With hydrazine; In pyridine; dichloromethane; adn. of hydrazine to Fe-complex (in absence of O2), cooling in liquid N2, bubbling O2, stirring and warming to room temp., stirring for further 20 min, washing (0.1 M aq. HCl); drying (Na2SO4), vol. reduction (vac.), hexane addn., collection (filtration), washing (hexane); further products on chromy. of mother liquor;

Reference yield: 40.0%

(2,3,7,8,12,13,17,18-octaethylporphyrin)iron(III) iodide (41697-73-8) + tetrabutyl-ammonium chloride (1112-67-0) → iron(III)octaethylporphyrin chloride (28755-93-3)

Guidance literature:

In not given; 1 equivalent of nBu4NCl added;

DOI:10.1246/cl.2003.526

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + {[Fe(octaethylporphyrin)]2(μ-N2O2)} → iron(III)octaethylporphyrin chloride (28755-93-3) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In toluene; byproducts: H2O; toluene soln. of Fe-complex reacted with HCl at 0°C; monitored by IR;

DOI:10.1021/ja809781r

upstream raw materials:

2,3,7,8,12,13,17,18-octaethylporphyrin

(octaethylporphyrin)Fe(p-MeC₆H₄)

(2,3,7,8,12,13,17,18-octaethylporphyrin)iron(III) iodide

tetrabutyl-ammonium chloride

Downstream raw materials:

peroxoferrioctaethylporphyrin^(1-), tetramethylammonium salt

Fe(2,3,7,8,12,13,17,18-octaethylporphyrinate)(nitrosobenzene)(1-methylimidazole)

[(octaethylporphyrinato)ferrous nitrosyl]

[NC₄(C₂H₅)2CH]4Fe(C₆F₅)

Refernces

• 1、 Migita, Catharina T.,Iwaizumi, Masamoto. "Low-Temperature EPR Studies of Highly Anisotropic Low-Spin (Protoporphyrinato)iron(III) Complexes". . p. 4378 - 4381. Retrieved 1981.
• 2、 Khorasani-Motlagh, Mozhgan,Safari, Nasser,Noroozifar, Meissam,Shahroosvand, Hashem,Patrick, Brian O.. "Synthesis and structural determination of new octaethylporphyrin iron(III) complexes containing cyanamide derivatives as axial ligand". . p. 1260 - 1266. Retrieved 2009/06/05.