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Potassium 3-methoxy-3-oxopropanoate

Base Information Edit
  • Chemical Name:Potassium 3-methoxy-3-oxopropanoate
  • CAS No.:38330-80-2
  • Molecular Formula:C4H5KO4
  • Molecular Weight:156.18
  • Hs Code.:29171910
  • European Community (EC) Number:253-886-8
  • DSSTox Substance ID:DTXSID90191698
  • Nikkaji Number:J294.646G
  • Mol file:38330-80-2.mol
Potassium 3-methoxy-3-oxopropanoate

Synonyms:Potassium 3-methoxy-3-oxopropanoate;38330-80-2;Methyl potassium malonate;Potassium methyl malonate;Potassium monomethyl malonate;Hydrogen Methyl Malonate Potassium Salt;Propanedioic acid, monomethyl ester, potassium salt;Monomethyl malonate potassium salt;potassium;3-methoxy-3-oxopropanoate;MFCD00014021;Monomethyl Potassium Malonate;EINECS 253-886-8;C4H5KO4;SCHEMBL344530;AMY3965;DTXSID90191698;WWTULTKUWBKVGV-UHFFFAOYSA-M;Potassium3-methoxy-3-oxopropanoate;CS-M3561;DITHIOLOXALICACIDDIPOTASSIUMSALT;AKOS015851411;Malonic acid 1-methyl 3-potassium salt;Malonic Acid Methyl Ester Potassium Salt;AS-18726;BP-23494;SY031346;3-methoxy-3-oxopropanoic acid potassium salt;FT-0628754;M2149;Malonic Acid Monomethyl Ester Potassium Salt;Propanedioic acid,1-methyl ester,potassium salt;10.14272/WWTULTKUWBKVGV-UHFFFAOYSA-M.1;A824114;doi:10.14272/WWTULTKUWBKVGV-UHFFFAOYSA-M.1;J-524007;carbanide;malonic acid

Suppliers and Price of Potassium 3-methoxy-3-oxopropanoate
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Usbiological
  • Hydrogen methyl malonate potassium salt
  • 50g
  • $ 342.00
  • TRC
  • HydrogenMethylMalonatePotassiumSalt
  • 500g
  • $ 415.00
  • TCI Chemical
  • Monomethyl Potassium Malonate >98.0%(T)
  • 25g
  • $ 40.00
  • TCI Chemical
  • Monomethyl Potassium Malonate >98.0%(T)
  • 250g
  • $ 229.00
  • SynQuest Laboratories
  • Methyl potassium malonate 98%
  • 500 g
  • $ 280.00
  • SynQuest Laboratories
  • Methyl potassium malonate 98%
  • 100 g
  • $ 95.00
  • SynQuest Laboratories
  • Methyl potassium malonate 98%
  • 250 g
  • $ 160.00
  • Sigma-Aldrich
  • Methyl potassium malonate ≥99.0% (NT)
  • 50g
  • $ 144.00
  • Sigma-Aldrich
  • Methyl potassium malonate ≥99.0% (NT)
  • 250g
  • $ 261.00
  • Matrix Scientific
  • Potassium 3-methoxy-3-oxopropanoate 98%
  • 100g
  • $ 710.00
Total 82 raw suppliers
Chemical Property of Potassium 3-methoxy-3-oxopropanoate Edit
Chemical Property:
  • Appearance/Colour:white crystalline powder 
  • Vapor Pressure:0.0211mmHg at 25°C 
  • Melting Point:200 °C 
  • Boiling Point:232.1 °C at 760 mmHg 
  • Flash Point:103.7 °C 
  • PSA:66.43000 
  • LogP:-1.70060 
  • Storage Temp.:Refrigerator 
  • Solubility.:Soluble in methanol. 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:4
  • Rotatable Bond Count:3
  • Exact Mass:155.98249012
  • Heavy Atom Count:9
  • Complexity:111
Purity/Quality:

99%, *data from raw suppliers

Hydrogen methyl malonate potassium salt *data from reagent suppliers

Safty Information:
  • Pictogram(s): IrritantXi 
  • Hazard Codes:Xi 
  • Statements: 36/37/38 
  • Safety Statements: 37/39-26 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Canonical SMILES:COC(=O)CC(=O)[O-].[K+]
  • Uses A protein advanced glycosylation inhibitor. Methyl potassium malonate is a protein advanced glycosylation inhibitor. Methyl potassium malonate can be used in the total synthesis of (±)-vincorine, an akuammiline alkaloid which can find applications in biology. It can also be used to synthesize a key keto proline ester intermediate to prepare acutumine.
Technology Process of Potassium 3-methoxy-3-oxopropanoate

There total 2 articles about Potassium 3-methoxy-3-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With potassium tert-butylate; water; In ethanol; at 40 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2012.01.032
Guidance literature:
With potassium hydroxide; at 10 - 35 ℃; for 14h;
Guidance literature:
In N,N-dimethyl-formamide; for 22h;
DOI:10.1139/v01-100
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