1,1-dimethyl-2-thioxohydrazine

Base Information

• Chemical Name: 1,1-dimethyl-2-thioxohydrazine
• CAS No.: 13066-27-8
• Molecular Formula: C₂H₆N₂S
• Molecular Weight: 90.149
• Mol file: 13066-27-8.mol

Synonyms:1,1-dimethyl-2-thioxohydrazine

Chemical Property of 1,1-dimethyl-2-thioxohydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-dimethyl-2-thioxohydrazine

There total 2 articles about 1,1-dimethyl-2-thioxohydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-Dimethylhydrazine (57-14-7) + acetone (67-64-1) → dimethyl tetrasulfide (5756-24-1) + Dimethyldisulphide (624-92-0) + dimethyltrisulfane (3658-80-8) + bis(dimethylamino)sulfide (2129-20-6) + N,N'-dithiobis-methanamine (928-05-2) + Acetone dimethylhydrazone (13483-31-3) + bis(dimethylamino) trisulfide (5669-44-3) + 1,1-dimethyl-2-thioxohydrazine (13066-27-8) + (dimethylamino) methyl trisulfide (1620476-75-6)

Guidance literature:

With sulfur;

DOI:10.1134/S1070363214060097

Reference yield:

N,N-Dimethylhydrazine (57-14-7) → dimethyl tetrasulfide (5756-24-1) + Dimethyldisulphide (624-92-0) + dimethyltrisulfane (3658-80-8) + bis(dimethylamino)sulfide (2129-20-6) + N,N'-dithiobis-methanamine (928-05-2) + N,N-dimethylthioformamide (758-16-7) + bis(dimethylamino) trisulfide (5669-44-3) + 1,1-dimethyl-2-thioxohydrazine (13066-27-8) + (dimethylamino) methyl tetrasulfide (1620476-76-7) + (dimethylamino) methyl trisulfide (1620476-75-6) + dimethylaminoacetaldehyde dimethylhydrazone

Guidance literature:

With sulfur;

DOI:10.1134/S1070363214060097

Reference yield: 98.0%

Ru(p-tolyl)Cl(CO)(PPh3)2 + 1,1-dimethyl-2-thioxohydrazine (13066-27-8) → Carbonylchloro(dimethylthionitrosamine-S)p-tolylbis(triphenylphosphine)ruthenium

Guidance literature:

In diethyl ether; toluene; (N2), suspn. of Ru-complex in toluene treated with a soln. of (CH3)2NNSin ether, stirred for 20 min; hexane added, pptn. filtered off, washed with hexane, recrystd. from CH2Cl2/ethanol, dried in vacuo, elem. anal.;

DOI:10.1016/0022-328X(86)80415-6

upstream raw materials:

N,N-Dimethylhydrazine

acetone

Downstream raw materials:

benzo[1,2,5]thiadiazole

Rh(C₈H₁₂)(SNN(CH₃)2)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)=(Rh(C₈H₁₂)(SNN(CH₃)2)(P(C₆H₅)3))ClO₄

cis,trans-(carbonyl-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-osmium) tetrafluoroborate

cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate

Refernces