bbenzo[d]thiazol-2-yldiphenylphosphine oxide

Base Information

• Chemical Name: bbenzo[d]thiazol-2-yldiphenylphosphine oxide
• CAS No.: 720675-16-1
• Molecular Formula: C₁₉H₁₄NOPS
• Molecular Weight: 335.366
• Mol file: 720675-16-1.mol

Synonyms:bbenzo[d]thiazol-2-yldiphenylphosphine oxide

Chemical Property of bbenzo[d]thiazol-2-yldiphenylphosphine oxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bbenzo[d]thiazol-2-yldiphenylphosphine oxide

There total 19 articles about bbenzo[d]thiazol-2-yldiphenylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,3-Benzothiazole (95-16-9) + Diphenylphosphine oxide (4559-70-0) → bbenzo[d]thiazol-2-yldiphenylphosphine oxide (720675-16-1)

Guidance literature:

With oxygen; In neat (no solvent); at 65 ℃; for 18h; Solvent; Temperature; Time; Green chemistry;

DOI:10.1021/acs.joc.6b00592

Reference yield: 87.0%

cyclohexyl(2-isocyanophenyl)sulfane + Diphenylphosphine oxide (4559-70-0) → bbenzo[d]thiazol-2-yldiphenylphosphine oxide (720675-16-1)

Guidance literature:

With oxygen; Rose Bengal lactone; In dimethyl sulfoxide; at 20 ℃; for 13h; Inert atmosphere; Irradiation; Green chemistry;

DOI:10.1016/j.cclet.2019.10.022

Reference yield: 81.0%

Diphenylphosphine oxide (4559-70-0) + (2-isocyanophenyl)(methyl)sulfane (175694-99-2) → bbenzo[d]thiazol-2-yldiphenylphosphine oxide (720675-16-1)

Guidance literature:

With manganese(III) triacetate dihydrate; In toluene; at 85 ℃; for 6h; Reagent/catalyst; Solvent; Inert atmosphere;

DOI:10.1021/acs.orglett.8b01278

upstream raw materials:

2-chlorobenzo[d][1,3]thiazole

Diphenylphosphine oxide

1,3-Benzothiazole

phenyl isothiocyanate

Downstream raw materials:

2-(diphenylphosphanyl)benzo[d]thiazole

Refernces

• 1、 Liu, Xiao-Ceng,Chen, Xiao-Lan,Liu, Yan,Sun, Kai,Peng, Yu-Yu,Qu, Ling-Bo,Yu, Bing. "Visible-Light-Induced Metal-Free Synthesis of 2-Phosphorylated Thioflavones in Water". . p. 298 - 303. Retrieved 2020.
• 2、 Luo, Kai,Chen, Yao-Zhong,Yang, Wen-Chao,Zhu, Jie,Wu, Lei. "Cross-coupling hydrogen evolution by visible light photocatalysis toward C(sp2)-P formation: Metal-free C-H functionalization of thiazole derivatives with diarylphosphine oxides". . p. 452 - 455. Retrieved 2016.
• 3、 Zhong, Kaipeng,Lu, Siyu,Guo, Wenting,Su, Junxia,Sun, Shihao,Hai, Jun,Chen, Fenjuan,Wang, Aiqin,Wang, Baodui. "Embedding CsPbBr3quantum dots into a pillar[5]arene-based supramolecular self-assembly for an efficient photocatalytic cross-coupling hydrogen evolution reaction". supporting information. p. 10180 - 10185. Retrieved 2021/05/04.