2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose

Base Information

• Chemical Name: 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose
• CAS No.: 914451-11-9
• Molecular Formula: C₂₇H₂₂O₇
• Molecular Weight: 458.467
• Mol file: 914451-11-9.mol

Synonyms:2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose

Chemical Property of 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose

There total 4 articles about 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 6-bromo-6-deoxy-2,3,4-tri-O-benzoyl-D-galactopyranoside (914451-05-1) → 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose (914451-11-9)

Guidance literature:

With cerium(III) chloride; ammonium chloride; zinc; In tetrahydrofuran; methanol; at 40 ℃; for 3h; sonification;

DOI:10.1021/jo061503b

Reference yield:

methyl D-galactopyranoside (97-30-3,617-04-9,709-50-2,1824-94-8,2152-78-5,3149-68-6,3396-99-4,6819-48-3,18469-06-2,20550-04-3,22277-65-2,29411-57-2,35437-40-2,35437-43-5,36191-11-4,36191-12-5,39598-79-3,39598-80-6,39598-89-5,51023-63-3,51223-62-2,51224-38-5,51224-39-6,51224-40-9,51224-41-0,51819-81-9,51819-82-0,51819-83-1,56688-81-4,62279-53-2,64281-79-4,64281-80-7,64912-19-2,66101-73-3,78184-90-4,84368-39-8,84368-40-1,84368-41-2,92142-37-5,93302-26-2,103421-28-9,115794-08-6) → 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose (914451-11-9)

Guidance literature:

Multi-step reaction with 4 steps

1: CHCl₃ / Heating

2: N-bromosuccinimide

3: CeCl₃; Zn

With N-Bromosuccinimide; cerium(III) chloride; zinc; In chloroform;

DOI:10.1080/15257770600793851

Reference yield:

(diethoxymethyl)benzene (774-48-1) → 2,3,4-tri-O-benzoyl-5,6-dideoxy-L-arabino-hex-5-enose (914451-11-9)

Guidance literature:

Multi-step reaction with 4 steps

1: CHCl₃ / Heating

2: N-bromosuccinimide

3: CeCl₃; Zn

With N-Bromosuccinimide; cerium(III) chloride; zinc; In chloroform;

DOI:10.1080/15257770600793851

upstream raw materials:

methyl 6-bromo-6-deoxy-2,3,4-tri-O-benzoyl-D-galactopyranoside

6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

methyl D-galactopyranoside

(diethoxymethyl)benzene

Downstream raw materials:

C₂₇H₂₅NO₇

C₃₀H₂₇NO₉

Refernces

• 1、 Hornyak,Kele,Kovacs,Forgo,Howarth. "Investigation of 1,3-dipolar cycloaddition reactions of unsaturated nitrones in ionic liquids". . p. 867 - 870. Retrieved 2007/10/03.