MoCl(η3-S2CPMe3)(NO)(PMe3)2

Base Information

• Chemical Name: MoCl(η3-S2CPMe3)(NO)(PMe3)2
• CAS No.: 119998-14-0
• Molecular Formula: C₁₀H₂₇ClMoNOP₃S₂
• Molecular Weight: 466.766
• Mol file: 119998-14-0.mol

Synonyms:MoCl(η3-S2CPMe3)(NO)(PMe3)2

Chemical Property of MoCl(η3-S2CPMe3)(NO)(PMe3)2

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of MoCl(η3-S2CPMe3)(NO)(PMe3)2

There total 2 articles about MoCl(η3-S2CPMe3)(NO)(PMe3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

trans-MoCl(NO)(PMe3)4 (119998-04-8) → MoCl(η3-S2CPMe3)(NO)(PMe3)2 (119998-14-0) + trimethylphosphane (594-09-2)

Guidance literature:

With CS₂; In tetrahydrofuran; Ar or N2 atmosphere; addn. of 1.4 equiv of CS2 to a soln. of Mo-complex, stirring (24 h at room temp.), pptn.; collection (filtration), washing (Et2O), crystn. (CHCl3), -30°C;

Reference yield:

trans-MoCl(NO)(PMe3)4 (119998-04-8) + [13C]carbon disulfide (30860-31-2) → MoCl(η3-S2CPMe3)(NO)(PMe3)2 (119998-14-0) + trimethylphosphane (594-09-2)

Guidance literature:

In tetrahydrofuran; Ar or N2 atmosphere; addn. of 1.4 equiv of CS2 (50% enriched in (13)CS2) to a soln. of Mo-complex, stirring (24 h at room temp.), pptn.; collection (filtration), washing (Et2O), crystn. (CHCl3), -30°C;

upstream raw materials:

trans-MoCl(NO)(PMe₃)4

[13C]carbon disulfide

Refernces