C₁₄H₁₆O₂P⁽¹⁺⁾*CF₃O₃S^(1-)

Base Information

• Chemical Name: C₁₄H₁₆O₂P⁽¹⁺⁾*CF₃O₃S^(1-)
• CAS No.: 23308-76-1
• Molecular Formula: CF₃O₃S*C₁₄H₁₆O₂P
• Molecular Weight: 396.324
• Mol file: 23308-76-1.mol

Synonyms:C₁₄H₁₆O₂P⁽¹⁺⁾*CF₃O₃S^(1-)

Chemical Property of C₁₄H₁₆O₂P⁽¹⁺⁾*CF₃O₃S^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₄H₁₆O₂P⁽¹⁺⁾*CF₃O₃S^(1-)

There total 2 articles about C₁₄H₁₆O₂P⁽¹⁺⁾*CF₃O₃S^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl trifluoromethanesulfonate (333-27-7) + methyl diphenylphosphinate (1706-90-7) → C14H16O2P(1+)*CF3O3S(1-) (23308-76-1)

Guidance literature:

In dichloromethane; Ambient temperature;

DOI:10.1021/ja00304a029

Reference yield:

trifluoromethanesulfonic acid ethyl ester (425-75-2) + methyl diphenylphosphinate (1706-90-7) → C14H16O2P(1+)*CF3O3S(1-) (23308-76-1)

Guidance literature:

In 1,1,2,2-tetrachloroethylene; at 75 ℃; for 16h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c5cc06389b

Reference yield:

C14H16O2P(1+)*CF3O3S(1-) (23308-76-1) → methyl diphenylphosphinate (1706-90-7)

Guidance literature:

With water; monochloroacetate; In dichloromethane; at 25 ℃; Rate constant; hydrolysis; further catalysts;

DOI:10.1021/ja00304a029

upstream raw materials:

methyl trifluoromethanesulfonate

methyl diphenylphosphinate

trifluoromethanesulfonic acid ethyl ester

Downstream raw materials:

methyl diphenylphosphinate

O-methyl P,P-diphenylphosphinite borane

Refernces

• 1、 McClelland, Robert A.,McGall, Glenn H.,Patel, Geeta. "Kinetics and Mechanism of the Hydrolysis of Acyclic Oxyphosphonium Salts". . p. 5204 - 5209. Retrieved 2007/10/02.