monacite

Base Information

• Chemical Name: monacite
• CAS No.: 721880-19-9
• Molecular Formula: Ce*O₄P
• Molecular Weight: 235.091
• Mol file: 721880-19-9.mol

Synonyms:monacite

Chemical Property of monacite

Chemical Property:

Purity/Quality:

(99.9%-Ce) ^*data from raw suppliers

Cerium(III) phosphate (99.9%-Ce) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of monacite

There total 20 articles about monacite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphoric acid (86119-84-8,7664-38-2) + cerium(IV) oxide → cerium orthophosphate (721880-19-9)

Guidance literature:

phosphoric acid; cerium(IV) oxide; In water; at 90 ℃; for 0.166667h;

With dihydrogen peroxide; In water; at 90 ℃;

DOI:10.1134/S0036023616100181

Reference yield:

cerium(III) chloride heptahydrate + phosphoric acid (86119-84-8,7664-38-2) → cerium orthophosphate (721880-19-9)

Guidance literature:

cerium(III) chloride heptahydrate; phosphoric acid; In water; for 6h;

With ammonium hydroxide; In water; pH=2-3;

at 1000 ℃; for 2h;

DOI:10.1134/S0036023616100181

Reference yield:

cerium(III) nitrate hexahydrate + phosphoric acid (86119-84-8,7664-38-2) → cerium orthophosphate (721880-19-9)

Guidance literature:

cerium(III) nitrate hexahydrate; With ammonia; In water; at 30 ℃;

phosphoric acid; In water; for 8h; Product distribution / selectivity;

upstream raw materials:

hypophosphorous acid

phosphoric acid

cerium(III) ion

cerium(III) chloride heptahydrate

Downstream raw materials:

phosphoric acid

Refernces

• 1、 Tang, Chengchun,Bando, Yoshio,Golberg, Dmitri,Ma, Renzhi. "Cerium phosphate nanotubes: Synthesis, valence state, and optical properties". . p. 576 - 579. Retrieved 2005.
• 2、 Karpowich,Wilcke,Yu, Rong,Harley,Reimer,De Jonghe. "Synthesis and characterization of mixed-morphology CePO4 nanoparticles". . p. 840 - 846. Retrieved 2007.
• 3、 Skogareva,Shekunova,Baranchikov,Yapryntsev,Sadovnikov,Ryumin,Minaeva,Ivanov. "Synthesis of cerium orthophosphates with monazite and rhabdophane structure from phosphoric acid solutions in the presence of hydrogen peroxide". . . Retrieved 2016.
• 4、 Fang, Yue-Ping,Xu, An-Wu,Song, Rui-Qi,Zhang, Hua-Xin,You, Li-Ping,Yu, Jimmy C.,Liu, Han-Qin. "Systematic Synthesis and Characterization of Single-Crystal Lanthanide Orthophosphate Nanowires". . p. 16025 - 16034. Retrieved 2003.
• 5、 Takita, Yusaku,Wakamatsu, Hironori,Li, Gong-Liang,Moro-Oka, Yoshihiko,Nishiguchi, Hiroyasu,Ishihara, Tatsumi. "Decomposition of chlorofluorocarbons over metal phosphate catalysis. II. Origin of the stability of AlPO4 and the location of CE as a promoter". . p. 111 - 119. Retrieved 2000.
• 6、 Hirai, Hidekazu,Masui, Toshiyuki,Imanaka, Nobuhito,Adachi, Gin-ya. "Characterization and thermal behavior of amorphous rare earth phosphates". . p. 84 - 88. Retrieved 2004.
• 7、 Bu, Wen-Bo,Hua, Zi-Le,Chen, Hang-Rong,Zhang, Ling-Xia,Shi, Jian-Lin. "Hydrothermal synthesis of ultraviolet-emitting cerium phosphate single-crystal nanowires". . p. 612 - 613. Retrieved 2004.
• 8、 MacAlik,Tomaszewski,Matraszek,Szczygie?,Solarz,Godlewska,Sobczyk,Hanuza. "Optical and structural characterisation of pure and Pr3+ doped LaPO4 and CePO4 nanocrystals". . p. 7458 - 7465. Retrieved 2011.
• 9、 Yu, Ranbo,Wang, Dan,Ishiwata, Shintaro,Saito, Takashi,Azuma, Masaki,Takano, Mikio,Chen, Yunfa,Li, Jinghai. "Synthesis and characterization of the first organically templated layered cerium phosphate fluoride: [(CH2)2(NH3) 2]0.5[CeIVF3(HPO4)]". . p. 458 - 459. Retrieved 2004.
• 10、 Cao, Lixin,Dong, Bohua,Gao, Rongjie,Li, Yanxin,Su, Ge,Wang, Ruonan,Zhou, Rui. "Two-phase synthesis of Fe doped cerium phosphate ultra-fine nanocrystals for efficient oxygen evolution". . p. 2609 - 2617. Retrieved 2022/02/22.