allyl 2-(2-nitrophenyl)acetate

Base Information

• Chemical Name: allyl 2-(2-nitrophenyl)acetate
• CAS No.: 1141874-17-0
• Molecular Formula: C₁₁H₁₁NO₄
• Molecular Weight: 221.213
• Mol file: 1141874-17-0.mol

Synonyms:allyl 2-(2-nitrophenyl)acetate

Chemical Property of allyl 2-(2-nitrophenyl)acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of allyl 2-(2-nitrophenyl)acetate

There total 1 articles about allyl 2-(2-nitrophenyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2-(2-nitrophenyl)acetic acid (3740-52-1) + allyl alcohol (107-18-6) → allyl 2-(2-nitrophenyl)acetate (1141874-17-0)

Guidance literature:

With sulfuric acid; Reflux; Inert atmosphere;

DOI:10.1071/CH13219

Reference yield: 91.0%

allyl 2-(2-nitrophenyl)acetate (1141874-17-0) + methyl 2-(bromomethyl)-3-phenylacrylate (103547-97-3,103669-71-2,53059-43-1) → C22H21NO6 (1141874-21-6)

Guidance literature:

With potassium carbonate; In acetonitrile; at 20 ℃; for 12h;

DOI:10.1016/j.tetlet.2009.01.151

Reference yield: 87.0%

allyl 2-(2-nitrophenyl)acetate (1141874-17-0) → 2-(2-nitrophenyl)acetic acid (3740-52-1)

Guidance literature:

allyl 2-(2-nitrophenyl)acetate; With sodium tetrahydroborate; In dimethyl sulfoxide; at 20 ℃;

With hydrogenchloride; water; In dimethyl sulfoxide; for 0.5h; chemoselective reaction;

DOI:10.1080/00397910902963694

upstream raw materials:

2-(2-nitrophenyl)acetic acid

allyl alcohol

Downstream raw materials:

C₁₂H₁₃NO₄

C₂₂H₂₁NO₆

C₁₇H₁₉NO₅

C₁₆H₁₇NO₅

Refernces

• 1、 Waetzig, Shelli R.,Tunge, Jon A.. "Palladium-catalyzed decarboxylative sp3-sp3 coupling of nitrobenzene acetic esters". . p. 14860 - 14861. Retrieved 2008/09/18.