trithiocarbonic acid bis(1-phenylethyl) ester

Base Information

• Chemical Name: trithiocarbonic acid bis(1-phenylethyl) ester
• CAS No.: 259195-14-7
• Molecular Formula: C₁₇H₁₈S₃
• Molecular Weight: 318.528
• Mol file: 259195-14-7.mol

Synonyms:trithiocarbonic acid bis(1-phenylethyl) ester

Chemical Property of trithiocarbonic acid bis(1-phenylethyl) ester

Chemical Property:

Purity/Quality:

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Technology Process of trithiocarbonic acid bis(1-phenylethyl) ester

There total 5 articles about trithiocarbonic acid bis(1-phenylethyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

carbon disulfide (75-15-0,12122-00-8) + (1-bromoethyl)benzne (585-71-7,38661-81-3) → trithiocarbonic acid bis(1-phenylethyl) ester (259195-14-7)

Guidance literature:

With caesium carbonate; In N,N-dimethyl acetamide; at 25 ℃; for 18h;

DOI:10.1055/s-2006-932480

Reference yield: 96.0%

1-phenylethyl p-toluenesulfonate (6749-54-8) → trithiocarbonic acid bis(1-phenylethyl) ester (259195-14-7)

Guidance literature:

With carbon disulfide; caesium carbonate; In dimethyl sulfoxide; at 20 - 25 ℃; for 5h; Inert atmosphere;

DOI:10.1007/s00706-008-0956-7

Reference yield: 81.0%

potassium trithiocarbonate (584-10-1) + (1-bromoethyl)benzne (585-71-7,38661-81-3) → trithiocarbonic acid bis(1-phenylethyl) ester (259195-14-7)

Guidance literature:

In N,N-dimethyl-formamide; at 50 ℃; for 10h;

DOI:10.1080/17415993.2012.731064

upstream raw materials:

carbon disulfide

(1-chloroethyl)benzene

(1-bromoethyl)benzne

1-phenylethyl p-toluenesulfonate

Downstream raw materials:

styrene

Refernces

• 1、 Tang, Boxin,White, Scott P.,Frisbie, C. Daniel,Lodge, Timothy P.. "Synergistic Increase in Ionic Conductivity and Modulus of Triblock Copolymer Ion Gels". . p. 4942 - 4950. Retrieved 2015.
• 2、 Movassagh, Barahman,Soleiman-Beigi, Mohammad,Nazari, Mohammad. "A facile KF/Al2O3-mediated, one-pot synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide". . p. 22 - 23. Retrieved 2008/09/20.