1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

Base Information

• Chemical Name: 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
• CAS No.: 95408-45-0
• Molecular Formula: C26H44 Cl2 Fe P2 Pd
• Molecular Weight: 651.756
• Hs Code.: 28439000
• Mol file: 95408-45-0.mol

Synonyms:Palladium,[1,1'-bis[bis(1,1-dimethylethyl)phosphino]ferrocene-P,P']dichloro-; Ferrocene,1,1'-bis[bis(1,1-dimethylethyl)phosphino]-, palladium complex;Dichloro(1,1'-bis(di-tert-butylphosphino)ferrocene)palladium

Chemical Property of 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

Chemical Property:

• Melting Point: 203-208 °C
• PSA: 27.18000
• LogP: 9.65990
• Storage Temp.: ?20°C
• Solubility.: Soluble in dichloromethane and chloroform. Partially soluble in

Purity/Quality:

99% ^*data from raw suppliers

[1,1''-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives. suzuki reaction 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride is used as a catalyst for the preparation of chalcones. Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.

Technology Process of 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

There total 2 articles about 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C24BF20(1-)*C26H46ClFeP2Pd(1+) → dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II) (95408-45-0)

Guidance literature:

With tetrabutylammomium bromide; In dichloromethane; Reagent/catalyst; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.organomet.5b00889

Reference yield:

C24BF20(1-)*C26H46ClFeP2Pd(1+) + bis(triphenylphosphine)iminium chloride (21050-13-5) → dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II) (95408-45-0)

Guidance literature:

In dichloromethane; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.organomet.5b00889

Reference yield: 61.0%

dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II) (95408-45-0) + potassium tetrakis(pentafluorophenyl)borate → C24BF20(1-)*C26H46ClFeP2Pd(1+)

Guidance literature:

In dichloromethane; for 0.25h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.organomet.5b00889

upstream raw materials:

bis(triphenylphosphine)iminium chloride

Refernces