[1,1'-biphenyl]-4-yltriethylsilane

Base Information

• Chemical Name: [1,1'-biphenyl]-4-yltriethylsilane
• CAS No.: 18057-71-1
• Molecular Formula: C₁₈H₂₄Si
• Molecular Weight: 268.474
• Mol file: 18057-71-1.mol

Synonyms:[1,1'-biphenyl]-4-yltriethylsilane

Chemical Property of [1,1'-biphenyl]-4-yltriethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [1,1'-biphenyl]-4-yltriethylsilane

There total 4 articles about [1,1'-biphenyl]-4-yltriethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

triethylsilane (617-86-7) + biphenyl-4-yl-trimethyl-ammonium; iodide (67402-10-2) → biphenyl (92-52-4,1594-86-1) + [1,1'-biphenyl]-4-yltriethylsilane (18057-71-1)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,3-bis[2,6-bis(diphenylmethyl)-4-methoxyphenyl]-1,3-dihydro-2H-imidazol-2-ium chloride; sodium t-butanolate; In 1,4-dioxane; at 40 ℃; Reagent/catalyst; Solvent; Catalytic behavior;

DOI:10.1039/c9sc01083a

Reference yield: 25.0%

triethylsilane (617-86-7) + 4-phenylphenyl triflate (17763-78-9) → biphenyl (92-52-4,1594-86-1) + [1,1'-biphenyl]-4-yltriethylsilane (18057-71-1)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; C₂₉H₄₀N₂*ClH; N,N′-bis(2,6-bis(diphenylmethyl)-4-methoxyphenyl)imidazol-2-ylidene; sodium t-butanolate; In toluene; at 120 ℃;

DOI:10.1021/acscatal.7b02025

Reference yield: 18.0%

triethylsilane (617-86-7) + ([1,1′-biphenyl]-4-yloxy)(tert-butyl)dimethylsilane → biphenyl (92-52-4,1594-86-1) + [1,1'-biphenyl]-4-yltriethylsilane (18057-71-1)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium-2-ide; sodium t-butanolate; In toluene; at 120 ℃;

DOI:10.1021/acscatal.7b02025

upstream raw materials:

triethylsilyl chloride

benzonitrile

triethylsilane

4-phenylphenyl triflate

Downstream raw materials:

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-iodo-biphenyl

4-bromo-1,1'-biphenyl

Refernces

• 1、 Rand, Alexander W.,Montgomery, John. "Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes". . p. 5338 - 5344. Retrieved 2019/05/29.