Iron,tetracarbonyl(phosphorous trifluoride)-

Base Information

• Chemical Name: Iron,tetracarbonyl(phosphorous trifluoride)-
• CAS No.: 16388-47-9
• Molecular Formula: C₄F₃FeO₄P
• Molecular Weight: 255.858
• Mol file: 16388-47-9.mol

Synonyms:Iron,(phosphorus trifluoride)tetracarbonyl- (7CI); Iron, tetracarbonyl(phosphorustrifluoride)- (8CI); Phosphorous trifluoride, iron complex; Phosphoroustrifluoride, iron deriv.; Tetracarbonyl(trifluorophosphine)iron

Chemical Property of Iron,tetracarbonyl(phosphorous trifluoride)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Iron,tetracarbonyl(phosphorous trifluoride)-

There total 2 articles about Iron,tetracarbonyl(phosphorous trifluoride)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) + trifluorophosphane (7783-55-3) + sulfur(VI) hexafluoride (2551-62-4) → {Fe(CO)4(PF3)} (16388-47-9,35739-13-0,53368-95-9) + {Fe(CO)3(PF3)2} (17594-23-9,17594-22-8,16454-87-8,53275-22-2) + {Fe(CO)2(PF3)3} (17594-25-1,17594-26-2,16388-46-8,53275-23-3) + {Fe(CO)(PF3)4} (17594-28-4,16388-45-7,17594-29-5) + {Fe(PF3)5} (13815-34-4)

Guidance literature:

In gas; byproducts: CO; other Radiation; irradiation of mixture of SF6 (0.5 Torr), Fe(CO)5 (0.2 Torr) and PF3 (10 Torr); gas chromy.;

DOI:10.1021/ja00189a007

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) + trifluorophosphane (7783-55-3) → {Fe(CO)4(PF3)} (16388-47-9,35739-13-0,53368-95-9) + {Fe(CO)3(PF3)2} (17594-23-9,17594-22-8,16454-87-8,53275-22-2) + {Fe(CO)2(PF3)3} (17594-25-1,17594-26-2,16388-46-8,53275-23-3) + {Fe(CO)(PF3)4} (17594-28-4,16388-45-7,17594-29-5) + Fe(PF3)5 (13815-34-4)

Guidance literature:

stainless steel bomb, 14-35 atm, 18h, PF3 rich products dominate at 240-300°C, CO rich ones below 200°C; pumping in vac. into a cold trop, at (-78--195°C) or distillation at room temp.;

DOI:10.1021/ic50020a011

upstream raw materials:

iron pentacarbonyl

trifluorophosphane

sulfur(VI) hexafluoride

Refernces

• 1、 Clark, Ronald J.. "Phosphorus trifluoride substitution compounds of iron pentacarbonyl". . p. 1395 - 1398. Retrieved 2008/10/08.