TBrPZ

Base Information

• Chemical Name: TBrPZ
• CAS No.: 890148-78-4
• Molecular Formula: C₂₁H₁₂Br₃N₃
• Molecular Weight: 546.058
• Mol file: 890148-78-4.mol

Synonyms:2,4,6-tris(3-bromophenyl)-1,3,5-triazine

Chemical Property of TBrPZ

Chemical Property:

• Melting Point: 207.0 to 211.0 °C
• Boiling Point: 661.4±65.0 °C(Predicted)
• PKA: 0.48±0.10(Predicted)
• Density: 1.741±0.06 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98% ^*data from raw suppliers

2,4,6-Tris(3-bromophenyl)-1,3,5-triazine >98.0%(HPLC)(N) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TBrPZ

There total 3 articles about TBrPZ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.6%

3-cyanobromobenzene (6952-59-6) → 2,4,6-tris(3-bromophenyl)-1,3,5-triazine (890148-78-4)

Guidance literature:

With trifluorormethanesulfonic acid; at 0 - 20 ℃; for 20h; Inert atmosphere;

Reference yield: 67.0%

m-bromobenzoic aldehyde (3132-99-8) → 2,4,6-tris(3-bromophenyl)-1,3,5-triazine (890148-78-4)

Guidance literature:

With iron(III) chloride; ammonium iodide; In toluene; at 130 ℃; for 15h; Sealed tube;

Reference yield:

→ 2,4,6-tris(3-bromophenyl)-1,3,5-triazine (890148-78-4)

Guidance literature:

With trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 48h;

upstream raw materials:

3-cyanobromobenzene

m-bromobenzoic aldehyde

Refernces

• 1、 Yin, Xiaojun,Chen, Dongcheng,Peng, Qiming,Xiang, Yepeng,Xie, Guohua,Zhu, Zece,Zhong, Cheng,Li, Feng,Su, Shijian,Yang, Chuluo. "Rational utilization of intramolecular and intermolecular hydrogen bonds to achieve desirable electron transporting materials with high mobility and high triplet energy". . p. 1482 - 1489. Retrieved 2016.
• 2、 Sorensen, Anne,Castilla, Ana M.,Ronson, Tanya K.,Pittelkow, Michael,Nitschke, Jonathan R.. "Chemical signals turn on guest binding through structural reconfiguration of triangular helicates". . p. 11273 - 11277. Retrieved 2013.
• 3、 Liu, Qiang,Ren, Shuang,Xiao, Jiang. "Atom-efficient synthesis of 2,4,6-trisubstituted 1,3,5-triazinesviaFe-catalyzed cyclization of aldehydes with NH4I as the sole nitrogen source". . p. 22230 - 22233. Retrieved 2020/07/03.
• 4、 -. "Triazine exciplex material based on phosphine and oxygen, preparation method and application thereof". Paragraph 0081. . Retrieved 2017/07/19.