1-Butenyl ethyl ether

Base Information

• Chemical Name: 1-Butenyl ethyl ether
• CAS No.: 929-05-5
• Molecular Formula: C6H12 O
• Molecular Weight: 100.161
• Hs Code.: 29091990
• European Community (EC) Number: 628-384-0,833-404-8
• DSSTox Substance ID: DTXSID501022517
• Nikkaji Number: J613.410F
• Mol file: 929-05-5.mol

Synonyms:1-BUTENYL ETHYL ETHER;929-05-5;1-ethoxybut-1-ene;1-Ethoxy-1-butene;1528-20-7;cis-1-Butenyl ethyl ether;trans-1-Butenyl ethyl ether;1-Butene, 1-ethoxy-, (E)-;trans-1-Ethoxy-1-butene;SCHEMBL892356;(1E)-1-Butenyl ethyl ether #;AQTYNINXYJFSHD-AATRIKPKSA-N;DTXSID501022517;(1E)-1-ETHOXYBUT-1-ENE;4884-01-9;1-Butenyl ethyl ether, cis + trans;MFCD03427069;AKOS037621867;EN300-137645

Chemical Property of 1-Butenyl ethyl ether

Chemical Property:

• Vapor Pressure: 48.6mmHg at 25°C
• Refractive Index: n20/D 1.4660(lit.)
• Boiling Point: 94-95 °C(lit.)
• Flash Point: 44 °F
• PSA: 9.23000
• Density: 0.778 g/mL at 25 °C(lit.)
• LogP: 1.94660
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 100.088815002
• Heavy Atom Count: 7
• Complexity: 48.1

Purity/Quality:

98%Min ^*data from raw suppliers

1-BUTENYL ETHYL ETHER, MIXTURE OF CIS AND TRANS 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=COCC
• Isomeric SMILES: CC/C=C/OCC

Technology Process of 1-Butenyl ethyl ether

There total 6 articles about 1-Butenyl ethyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1,1-diethoxybutane (3658-95-5) → ethanol (64-17-5) + 1-ethoxybut-1-ene (929-05-5)

Guidance literature:

With dimethisoquin; phosphoric acid; Heating;

Reference yield:

1,1-diethoxybutane (3658-95-5) → 1-ethoxybut-1-ene (929-05-5)

Guidance literature:

With sodium trisilicate; magnesium hydrogen phosphate; at 325 ℃;

Reference yield:

butyraldehyde (123-72-8) + orthoformic acid triethyl ester (122-51-0) → 1,1-diethoxybutane (3658-95-5) + 1-ethoxybut-1-ene (929-05-5) + formic acid ethyl ester (109-94-4)

Guidance literature:

With ammonium dihydrogen phosphate; Celite; toluene-4-sulfonic acid; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) 60 deg C, 4 h, 2.) 140 deg C, 6 h;

DOI:10.1080/15257779508010722

upstream raw materials:

1,1-diethoxybutane

dianilunium sulphate

4-aminobenzene sulfonic acid

butyraldehyde

Downstream raw materials:

3-ethoxy-4-ethyl-2-(toluene-4-sulfonyl)-[1,2]thiazetidine 1-oxide

2-[1-Ethoxy-meth-(Z)-ylidene]-N-(2,2,2-trichloro-acetyl)-butyramide

C₁₂H₁₆O

1-(phenylthio)butyl ethyl ether

Refernces

• 1、 Callot, Henry J.,Louati, Abderrazak,Gross, Maurice. "Synthesis and cyanation of octaalkylporphyrins using electrochemical methods". . p. 317 - 320. Retrieved 2007/10/02.