dibenzyl-2,2'-⁽¹³⁾C₂ ketone

Base Information

• Chemical Name: dibenzyl-2,2'-⁽¹³⁾C₂ ketone
• CAS No.: 77787-71-4
• Molecular Formula: C₁₅H₁₄O
• Molecular Weight: 212.254
• Mol file: 77787-71-4.mol

Synonyms:dibenzyl-2,2'-⁽¹³⁾C₂ ketone

Chemical Property of dibenzyl-2,2'-⁽¹³⁾C₂ ketone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibenzyl-2,2'-⁽¹³⁾C₂ ketone

There total 5 articles about dibenzyl-2,2'-⁽¹³⁾C₂ ketone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

α-phenylacetic acid-13C (68661-15-4) → dibenzyl-2,2'-(13)C2 ketone (77787-71-4)

Guidance literature:

With iron; at 320 ℃;

DOI:10.1021/ja000072q

Reference yield:

<α-13C>Benzolacetonitril (73368-35-1) → dibenzyl-2,2'-(13)C2 ketone (77787-71-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 100 percent / H₂SO₄, H₂O

2: 80 percent / C₂H₅ONa / ethanol

3: aq. H₂SO₄

With sulfuric acid; water; sodium ethanolate; In ethanol;

DOI:10.1021/ja00403a045

Reference yield:

C9(13)CH12O2 → dibenzyl-2,2'-(13)C2 ketone (77787-71-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / C₂H₅ONa / ethanol

2: aq. H₂SO₄

With sulfuric acid; sodium ethanolate; In ethanol;

DOI:10.1021/ja00403a045

upstream raw materials:

1-(13C)benzoic acid

α-phenylacetic acid-13C

<α-13C>Benzolacetonitril

Downstream raw materials:

tetraphenylcyclopentadienone-13C₂

benzyl chloride

1,1'-(1,2-ethanediyl)bisbenzene

[α-¹³C]benzyl

Refernces

• 1、 Musicki, Branislav. "Reaction of Pyrroloimidazole Mesomeric Betaines with Diphenylcyclopropenone Derivatives". . p. 110 - 118. Retrieved 2007/10/02.