(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate

Base Information

• Chemical Name: (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
• CAS No.: 866641-66-9
• Molecular Formula: C22H30AuF6NPSb
• Molecular Weight: 772.168
• European Community (EC) Number: 624-004-2
• DSSTox Substance ID: DTXSID30586948
• Wikidata: Q61962863
• Mol file: 866641-66-9.mol

Synonyms:866641-66-9;(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate;(Acetonitrile)[(biphenyl-2-yl)di-tert-butylphosphine]gold(1+) hexafluoroantimonate;acetonitrile;ditert-butyl-(2-phenylphenyl)phosphane;gold(1+);hexafluoroantimony(1-);(Acetonitrile)[(biphenyl-2-yl)di-tert-butylphosphine]gold(I) hexafluoroantimonate;DTXSID30586948;ADQOZROJMVWPRI-UHFFFAOYSA-H;SY067084;D97404;A863092;Q61962863;gold(1+) [1,1'-biphenyl]-2-yldi-tert-butyl)phosphane acetonitrile hexafluoroantimonate ion

Chemical Property of (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate

Chemical Property:

• Melting Point: 198-203 °C (D)
• PSA: 37.38000
• LogP: 9.10638
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: air sensitive, moisture sensitiv
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 4
• Exact Mass: 771.07239
• Heavy Atom Count: 32
• Complexity: 392

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate, 99% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N
• Statements: 20/22-51/53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC#N.CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2)C(C)(C)C.F[Sb-](F)(F)(F)(F)F.[Au+]

Technology Process of (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate

There total 1 articles about (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Ph3P-Au-(NCCH3)](1+)*SbF6(1-) (883995-03-7) + Au(4-picoline)(tBu)2P(C6H4C6H5) (1426437-86-6) → Echavarren's catalyst (866641-66-9) + C24H22AuNP(1+)*F6Sb(1-) (1426437-80-0)

Guidance literature:

In chloroform-d1; at 26.1 ℃; Equilibrium constant;

DOI:10.1021/om400083f

Reference yield: 100.0%

Echavarren's catalyst (866641-66-9) + hex-1-yne (693-02-7) → C46H63Au2P2(1+)*F6Sb(1-)

Guidance literature:

With sodium hydrogencarbonate; In chloroform-d1; water;

DOI:10.1002/anie.201402557

Reference yield: 99.0%

3-(2-phenylethynyl)oxazolidin-2-one (888329-88-2) + Echavarren's catalyst (866641-66-9) → C31H36AuNO2P(1+)*F6Sb(1-)

Guidance literature:

In hexane; dichloromethane; at -18 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.joc.6b01948

upstream raw materials:

[Ph₃P-Au-(NCCH₃)]⁽¹⁺⁾*SbF₆^(1-)

Au(4-picoline)(tBu)2P(C₆H₄C₆H₅)

Downstream raw materials:

(C₆H₅C₆H₄P(C(CH₃)3)2Au)2C₄H₃O⁽¹⁺⁾*SbF₆^(1-)=[(C₆H₅C₆H₄P(C(CH₃)3)2Au)2C₄H₃O](SbF₆)

C₆₀H₈₁Au₃P₃S⁽¹⁺⁾

C₃₈H₄₂AuP₂⁽¹⁺⁾*F₆Sb^(1-)

5-propyl-2,3-dihydrofuran

Refernces