benzothiaferrole

Base Information

• Chemical Name: benzothiaferrole
• CAS No.: 12086-84-9
• Molecular Formula: C₁₄H₆Fe₂O₆S
• Molecular Weight: 413.958
• Mol file: 12086-84-9.mol

Synonyms:benzothiaferrole

Chemical Property of benzothiaferrole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzothiaferrole

There total 1 articles about benzothiaferrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

triiron dodecarbonyl (17685-52-8) + Benzo[b]thiophene (95-15-8,11095-43-5) → iron pentacarbonyl (13463-40-6,37220-42-1) + benzothiaferrole (12086-84-9)

Guidance literature:

In benzene; refluxing (benzene, 18 h, N2); filtn. through Celite, concn. of filtrate, sublimation (first 25-30, then 80-90°C, 0.02 mmHg), elem. anal.;

DOI:10.1021/om00095a024

Reference yield: 63.0%

benzothiaferrole (12086-84-9) → 2-thiocoumarin (3986-98-9) + iron (7439-89-6) + Benzo[b]thiophene (95-15-8,11095-43-5)

Guidance literature:

flash vac. pyrolysis in a Pyrex tube connected with a cold trap (E-5 Torr, 285-315°C); coating of the hot zone by Fe, rinsing of trap with acetone, GC;

DOI:10.1021/om00095a024

Reference yield: 50.0%

benzothiaferrole (12086-84-9) → iron pentacarbonyl (13463-40-6,37220-42-1) + Benzo[b]thiophene (95-15-8,11095-43-5)

Guidance literature:

With CO; In hexane; loading an autoclave cup with Fe-compound in hexane and CO (500 psig, 25°C), heating (160°C, 700 psig, 19 h); cooling, transferring of soln. to a Schlenk flask (N2), GC and IR;

DOI:10.1021/om00095a024

upstream raw materials:

triiron dodecarbonyl

Benzo[b]thiophene

Downstream raw materials:

bis(2-ethylphenyl) sulfide

ethylbenzene

2-ethylthiophenol

1,2-bis(2-ethylphenyl) disulfide

Refernces