2,2'-dicarboxyltriphenylamine

Base Information

• Chemical Name: 2,2'-dicarboxyltriphenylamine
• CAS No.: 109747-49-1
• Molecular Formula: C₂₀H₁₅NO₄
• Molecular Weight: 333.343
• Mol file: 109747-49-1.mol

Synonyms:2,2'-dicarboxyltriphenylamine

Chemical Property of 2,2'-dicarboxyltriphenylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2'-dicarboxyltriphenylamine

There total 7 articles about 2,2'-dicarboxyltriphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C38H27N5O2 → 8-amino quinoline (578-66-5) + 2,2'-dicarboxyltriphenylamine (109747-49-1)

Guidance literature:

With sodium hydroxide; In methanol; at 120 ℃;

DOI:10.1021/acscatal.7b00262

Reference yield:

N-quinolin-8-yl-benzamide (33757-48-1) → 8-amino quinoline (578-66-5) + 2,2'-dicarboxyltriphenylamine (109747-49-1)

Guidance literature:

Multi-step reaction with 2 steps

1: cobalt(II) diacetate tetrahydrate; cesium acetate; oxygen; silver carbonate / 12 h / 90 °C

2: sodium hydroxide / methanol / 120 °C

With oxygen; cesium acetate; cobalt(II) diacetate tetrahydrate; silver carbonate; sodium hydroxide; In methanol;

DOI:10.1021/acscatal.7b00262

Reference yield:

N-quinolin-8-yl-benzamide (33757-48-1) + aniline (62-53-3) → 8-amino quinoline (578-66-5) + 2,2'-dicarboxyltriphenylamine (109747-49-1)

Guidance literature:

Multi-step reaction with 2 steps

1: cobalt(II) diacetate tetrahydrate; ferrocene; cesium acetate; oxygen / 12 h / 100 °C

2: sodium hydroxide / methanol / 120 °C

With ferrocene; oxygen; cesium acetate; cobalt(II) diacetate tetrahydrate; sodium hydroxide; In methanol;

DOI:10.1021/acscatal.7b00262

upstream raw materials:

2-(phenylamino)benzoic acid

o-iodo-methyl-benzoic acid

2,2'-(Phenylimino)bisbenzoesaeure-dimethylester

aniline

Downstream raw materials:

C₃₆H₃₃N₃O₄

Refernces

• 1、 Field, Jason E.,Venkataraman. "Helix versus zig-zag: Control of supramolecular topology via carboxylic acid conformations in ortho-substituted phenyl amines". . p. 306 - 307. Retrieved 2007/10/03.