4-Chloro-benzenethiol anion

Base Information

• Chemical Name: 4-Chloro-benzenethiol anion
• CAS No.: 35337-68-9
• Molecular Formula: C₆H₄ClS
• Molecular Weight: 143.617
• Mol file: 35337-68-9.mol

Synonyms:4-Chloro-benzenethiol anion

Chemical Property of 4-Chloro-benzenethiol anion

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Chloro-benzenethiol anion

There total 13 articles about 4-Chloro-benzenethiol anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

S-acetyl-4-chlorothiophenol (21021-60-3) → acetamide (60-35-5) + 4-Chloro-benzenethiol anion (35337-68-9)

Guidance literature:

With potassium chloride; ammonium chloride; ammonia; In 1,4-dioxane; water; at 18 ℃; pH=9.40; Further Variations:; pH-values; Kinetics;

DOI:10.1002/kin.10014

Reference yield:

S-(4-chlorophenyl) thiocarbamate (95062-74-1) → 4-Chloro-benzenethiol anion (35337-68-9) + isocyanic acid (75-13-8)

Guidance literature:

With hydroxide; In water; at 25 ℃; Rate constant; pH 6.0-7.5;

Reference yield:

phenyl-thiocarbamic acid (S)-4-chlorophenyl ester (64651-83-8) → 4-Chloro-benzenethiol anion (35337-68-9) + phenyl isocyanate (103-71-9)

Guidance literature:

With hydroxide; In water; at 25 ℃; Rate constant; pH 5.84-6.26;

upstream raw materials:

Nitroethane

4,4'-dichlorodiphenyl disulfide

hydrogen cyanide

phenyl-thiocarbamic acid (S)-4-chlorophenyl ester

Downstream raw materials:

2-(4-chloro-phenylsulfanylmethyl)-5-nitro-furan

[Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄]

2-(4-chlorophenylsulfanyl)pyridinium-N-(4-tolyl)imide

3,5-Dinitro-2-pyridyl-p-chlorphenylsulfid

Refernces

• 1、 Rajarathnam,Babu,Nadar, P. Ananthakrishna. "Enhanced reactivity in the ammonolysis of phenyl thiolacetates in aqueous medium". . p. 18 - 26. Retrieved 2007/10/03.
• 2、 Eldin, Sherif,Jencks, William P.. "Lifetimes of iminium ions in aqueous solution". . p. 4851 - 4857. Retrieved 2007/10/02.