trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester

Base Information

• Chemical Name: trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester
• CAS No.: 17352-13-5
• Molecular Formula: C₇H₄F₁₂O₆S₂
• Molecular Weight: 476.218
• Mol file: 17352-13-5.mol

Synonyms:trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester

Chemical Property of trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester

There total 2 articles about trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,3,3,4,4-hexafluoro-1,5-pentanediol (376-90-9) + Trifluoromethanesulfonyl fluoride (335-05-7) + triethylamine (121-44-8) → trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester (17352-13-5) + triethylamine hydrofluoride (23588-89-8,29585-72-6,94527-74-9)

Guidance literature:

In dichloromethane;

DOI:10.1021/jo01023a511

Reference yield:

2,2,3,3,4,4-hexafluoro-1,5-pentanediol (376-90-9) + trifluoromethane sulfonyl chloride (421-83-0) + triethylamine (121-44-8) → trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester (17352-13-5) + triethylamine hydrofluoride (23588-89-8,29585-72-6,94527-74-9)

Guidance literature:

In dichloromethane;

Reference yield: 89.0%

trifluoromethanesulfonic acid 2,2,3,3,4,4-hexafluoro-1,5-pentanediyl ester (17352-13-5) + 1,4-phenylenediamine (106-50-3) → 4-(3,3,4,4,5,5-hexafluoropiperidin-1-yl)aniline

Guidance literature:

With triethylamine; In ethanol; at 90 ℃; for 30h; Sealed tube;

DOI:10.1002/asia.201402576

upstream raw materials:

2,2,3,3,4,4-hexafluoro-1,5-pentanediol

trifluoromethane sulfonyl chloride

triethylamine

Trifluoromethanesulfonyl fluoride

Downstream raw materials:

3,3,4,4,5,5-hexafluoro-1-(phenylmethyl)piperidine