Magnesium, bromo-1,2-propadienyl-(9CI)

Base Information

• Chemical Name: Magnesium, bromo-1,2-propadienyl-(9CI)
• CAS No.: 18295-60-8
• Molecular Formula: C₃H₃BrMg
• Molecular Weight: 143.266
• DSSTox Substance ID: DTXSID501300266
• Mol file: 18295-60-8.mol

Synonyms:18295-60-8;Magnesium, bromo-1,2-propadienyl- (9CI);DTXSID501300266;magnesium;propa-1,2-diene;bromide;Magnesium, bromo-1,2-propadienyl-

Chemical Property of Magnesium, bromo-1,2-propadienyl-(9CI)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 141.92685
• Heavy Atom Count: 5
• Complexity: 29.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=C=[CH-].[Mg+2].[Br-]

Technology Process of Magnesium, bromo-1,2-propadienyl-(9CI)

There total 9 articles about Magnesium, bromo-1,2-propadienyl-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propargyl bromide (106-96-7) → allenylmagnesium bromide (18295-60-8)

Guidance literature:

With magnesium; mercury dichloride; In diethyl ether;

DOI:10.1021/jo9913199

Reference yield:

propargyl bromide (106-96-7) → propargyl magnesium bromide (18295-60-8)

Guidance literature:

With magnesium; mercury dichloride; In diethyl ether; toluene;

DOI:10.1021/jo00288a038

Reference yield:

magnesium (7439-95-4) + propargyl bromide (106-96-7) → propargyl magnesium bromide (18295-60-8)

Guidance literature:

mercury dichloride; In diethyl ether; at 0 - 5 ℃; for 1h;

upstream raw materials:

propargyl bromide

magnesium

disiloxane

furfural

Downstream raw materials:

dec-1-yn-4-ol

1-Heptyne

1,2-Heptadiene

2,2,6-trimethyl-1-prop-2-ynyl-cyclohexanol

Refernces

• 1、 Vasilyeva, T. P.,Vorobyeva, D. V.. "Synthesis of furanyl- and triazolyl-containing α-CF3-α-hydroxy acids and their derivatives". . p. 300 - 304. Retrieved 2020.
• 2、 Ratsch, Friederike,Schlundt, Waldemar,Albat, Dominik,Zimmer, Anne,Neud?rfl, J?rg-Martin,Netscher, Thomas,Schmalz, Hans-Günther. "Total Synthesis of α-Tocopherol through Enantioselective Iridium-Catalyzed Fragmentation of a Spiro-Cyclobutanol Intermediate". supporting information. p. 4941 - 4945. Retrieved 2019/03/21.