C₃₆H₄₃NO₈Si

Base Information

• Chemical Name: C₃₆H₄₃NO₈Si
• CAS No.: 158818-82-7
• Molecular Formula: C₃₆H₄₃NO₈Si
• Molecular Weight: 645.825
• Mol file: 158818-82-7.mol

Synonyms:C₃₆H₄₃NO₈Si

Chemical Property of C₃₆H₄₃NO₈Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₄₃NO₈Si

There total 1 articles about C₃₆H₄₃NO₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

triisopropylsilyl trifluoromethanesulfonate (80522-42-5) + C27H23NO8 → C36H43NO8Si (158818-82-7)

Guidance literature:

With triethylamine; In tetrahydrofuran; at -78 - 0 ℃;

DOI:10.1021/ja00104a041

Reference yield:

C36H43NO8Si (158818-82-7) → dynemicin A (124412-57-3,134527-29-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 78 percent / Bu₃SnH, Pd(PPh₃)2Cl₂, H₂O / CH₂Cl₂ / 0.17 h / 23 °C

2: 75 percent / tetrahydrofuran / -20 - 55 °C

3: 53 mg / MnO₂, Et₃N, HF / tetrahydrofuran / 0.15 h / 23 °C

With manganese(IV) oxide; bis-triphenylphosphine-palladium(II) chloride; hydrogen fluoride; water; tri-n-butyl-tin hydride; triethylamine; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja9703741

upstream raw materials:

triisopropylsilyl trifluoromethanesulfonate

Downstream raw materials:

dynemicin A

Refernces