Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Base Information

• Chemical Name: Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine
• CAS No.: 203192-36-3
• Molecular Formula: C₂₄H₃₂ClNNiP₃*F₆P
• Molecular Weight: 666.553
• Mol file: 203192-36-3.mol

Synonyms:Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Chemical Property of Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine

There total 2 articles about Ni(II)Cl(P(CH₃)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.5%

potassium hexafluorophosphate (17084-13-8) + trans-[dichlorobis(trimethylphosphane)nickel(II)] (103421-62-1,19232-05-4,20087-67-6) + (2-diphenylphosphino)benzeneamine (65423-44-1) → C36H30N2NiP2 (85096-37-3) + cis-Ni(II)(o-diphenylphosphino)aniline (PF6)2 + Ni(II)Cl(P(CH3)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine (203192-36-3)

Guidance literature:

In dichloromethane; byproducts: H2, KCl; N-compd. (solid) addn. to mixture of Ni-compd. and KPF6 soln., stirring(3 h, room temp., under N2), pptn. filtered off, filtrate concn., Et2O addn., solid after vigorous stirring; solid filtration off, washing (water, Et2O, MeOH), recrystn. (CH2Cl2/MeOH/C6H6 3/1/3), vac. drying;

DOI:10.1021/ja9738440

Reference yield: 9.0%

potassium hexafluorophosphate (17084-13-8) + Ni(II)Cl2P(CH3)3 (o-diphenylphosphino)aniline → Ni(II)Cl(P(CH3)3) (o-diphenylphosphino)-N-(trimethylphosphoranyl)phenylimine (203192-36-3)

Guidance literature:

In dichloromethane; KPF6 addn., stirring (room temp., 3 h); inorg. salts filtration off, filtrate concn., Et2O addn., solid after stirring; dissoln. (EtOH), standing (3 d), crystn.;

DOI:10.1021/ja9738440

upstream raw materials:

potassium hexafluorophosphate

trans-[dichlorobis(trimethylphosphane)nickel(II)]

(2-diphenylphosphino)benzeneamine

Refernces