(C₅H₅)(C₅H₄CH₃)TiCH₂Al(CH₃)2Cl

Base Information

• Chemical Name: (C₅H₅)(C₅H₄CH₃)TiCH₂Al(CH₃)2Cl
• CAS No.: 87729-05-3
• Molecular Formula: C₁₄H₂₀AlClTi
• Molecular Weight: 298.627
• Mol file: 87729-05-3.mol

Synonyms:(C₅H₅)(C₅H₄CH₃)TiCH₂Al(CH₃)2Cl

Chemical Property of (C₅H₅)(C₅H₄CH₃)TiCH₂Al(CH₃)2Cl

Chemical Property:

Purity/Quality:

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Technology Process of (C₅H₅)(C₅H₄CH₃)TiCH₂Al(CH₃)2Cl

There total 1 articles about (C₅H₅)(C₅H₄CH₃)TiCH₂Al(CH₃)2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + (h(5)-methylcyclopentadienyl)(h(5)-cyclopentadienyl)titanium dichloride (1282-43-5) + trimethylaluminum (75-24-1) → Tebbe's reagent + (C5H5)(C5H4CH3)TiCH2Al(CH3)2Cl (87729-05-3) + dimethylaluminum chloride (1184-58-3)

Guidance literature:

In toluene; Al(CH3)3 soln. added to (C5H4(CH3))(C5H5)TiCl2 (Ar) contg. impurity of (C5H5)2TiCl2, stirred for 40 h at room temp., solvent and Al(CH3)2Cl removed (vac.), dissolved in toluene, Al(CH3)3 soln. added, stirred for 12 h; solvent removed (vac.), , extd. (hexane), concd., cooled to -50°C, powder washed with hexane, dried (vac.);

DOI:10.1021/om00080a010

Reference yield: 48.0%

(C5H5)(C5H4CH3)TiCH2Al(CH3)2Cl (87729-05-3) + diphenyl acetylene (501-65-5) → (C5H5)(C5H4CH3)TiCH2C(C6H5)C(C6H5) (113110-40-0)

Guidance literature:

In tetrahydrofuran; THF soln. of (C5H5)(C5H4CH3)TiCH2Al(CH3)2Cl and diphenylacetylene stirred at 0 ° C for 0.5 h, warmed to room temp. and stirred again for 15 min; volatiles removed in vacuo, remaining residue dissolved in pentane and toluene and cooled to -50 ° C; dark purple crystals collected; elem. anal.;

DOI:10.1021/ja00216a012

upstream raw materials:

bis(cyclopentadienyl)titanium dichloride

(h⁽⁵⁾-methylcyclopentadienyl)(h⁽⁵⁾-cyclopentadienyl)titanium dichloride

trimethylaluminum

Downstream raw materials:

(C₅H₅)(C₅H₄CH₃)TiCH₂C(C₆H₅)C(C₆H₅)

Refernces