4-bromophenyl dithiocarbamic acid triethylammonium

Base Information

• Chemical Name: 4-bromophenyl dithiocarbamic acid triethylammonium
• CAS No.: 53662-49-0
• Molecular Formula: C₆H₁₅N*C₇H₆BrNS₂
• Molecular Weight: 349.359
• Mol file: 53662-49-0.mol

Synonyms:4-bromophenyl dithiocarbamic acid triethylammonium

Chemical Property of 4-bromophenyl dithiocarbamic acid triethylammonium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-bromophenyl dithiocarbamic acid triethylammonium

There total 2 articles about 4-bromophenyl dithiocarbamic acid triethylammonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.4%

→ 4-bromophenyl dithiocarbamic acid triethylammonium (53662-49-0)

Guidance literature:

In diethyl ether; at 20 ℃; for 10h;

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + triethylamine (121-44-8) + 4-bromo-aniline (106-40-1) → 4-bromophenyl dithiocarbamic acid triethylammonium (53662-49-0)

Guidance literature:

In diethyl ether;

DOI:10.1007/BF00810842

Reference yield: 98.0%

4-bromophenyl dithiocarbamic acid triethylammonium (53662-49-0) → 4-Bromophenyl isothiocyanate (1985-12-2)

Guidance literature:

With iodine; triethylamine; In acetonitrile; at 5 ℃; Cooling with ice;

DOI:10.1002/ejoc.200801270

upstream raw materials:

carbon disulfide

triethylamine

4-bromo-aniline

Downstream raw materials:

4-Bromophenyl isothiocyanate

1-(4-bromophenyl)-1H-tetrazole-5-thiol

N-(4-bromophenyl)cyanamide

3-(4-bromo-phenyl)-2-thioxo-2,3-dihydro-1H-quinazolin-4-one

Refernces

• 1、 Fu, Zhicheng,Yuan, Wenhao,Chen, Ning,Yang, Zhanhui,Xu, Jiaxi. "Na2S2O8-mediated efficient synthesis of isothiocyanates from primary amines in water". . p. 4484 - 4491. Retrieved 2018/10/17.
• 2、 Patil, Suresh,Jadhav,Shejwal,Deshmukh. "Microwave-assisted cyclocondensation for the synthesis of 3-Aryl-2-thioquinazolin-4(3h)-ones". scheme or table. p. 1858 - 1860. Retrieved 2012/08/13.