dichloro(methylthio)acetaldehyde

Base Information

• Chemical Name: dichloro(methylthio)acetaldehyde
• CAS No.: 101010-58-6
• Molecular Formula: C₃H₄Cl₂OS
• Molecular Weight: 159.036
• Mol file: 101010-58-6.mol

Synonyms:dichloro(methylthio)acetaldehyde

Chemical Property of dichloro(methylthio)acetaldehyde

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of dichloro(methylthio)acetaldehyde

There total 3 articles about dichloro(methylthio)acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dimethyl(1-chloro-2-hydroxyethenyl)sulfonium chloride (101010-52-0) → 2-(methylthio)acetaldehyde (23328-62-3) + 2,2,-bis(methylsulfanyl)acetaldehyde (101010-59-7) + chloro(methylthio)acetaldehyde (101010-56-4) + dichloro(methylthio)acetaldehyde (101010-58-6)

Guidance literature:

at 170 ℃; for 0.333333h; under 2 Torr; Further byproducts given;

DOI:10.1021/jo00358a026

Reference yield: 16.0%

dimethyl(1-chloro-2-hydroxyethenyl)sulfonium chloride (101010-52-0) → 2,2-dichloroacetaldehyde (79-02-7) + 2,2,-bis(methylsulfanyl)acetaldehyde (101010-59-7) + chloro(methylthio)acetaldehyde (101010-56-4) + dichloro(methylthio)acetaldehyde (101010-58-6)

Guidance literature:

at 170 ℃; for 0.333333h; under 2 Torr; Further byproducts given;

DOI:10.1021/jo00358a026

Reference yield:

dimethyl(1-chloro-2-hydroxyethenyl)sulfonium chloride (101010-52-0) → 2-(methylthio)acetaldehyde (23328-62-3) + 2,2-dichloroacetaldehyde (79-02-7) + 2,2,-bis(methylsulfanyl)acetaldehyde (101010-59-7) + chloro(methylthio)acetaldehyde (101010-56-4) + dichloro(methylthio)acetaldehyde (101010-58-6) + S-methyl bis(methylsulfanyl)thioacetate (101010-60-0)

Guidance literature:

at 170 ℃; for 0.333333h; under 2 Torr; Product distribution;

DOI:10.1021/jo00358a026

upstream raw materials:

dimethyl(1-chloro-2-hydroxyethenyl)sulfonium chloride

Refernces